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Dense Metal Membranes for the Production of High-Purity Hydrogen

Published online by Cambridge University Press:  31 January 2011

David S. Sholl  and
Y.H. Ma
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Abstract

Dense metal membranes are a well-developed technology for the production of high-purity hydrogen. The physical mechanism of hydrogen transport across metal films—dissociation of molecular hydrogen, diffusion of interstitial atomic hydrogen, and subsequent recombinative desorption of molecular hydrogen—means that metal membranes can have extremely high selectivities for hydrogen transport relative to other gases. We describe current experimental and theoretical trends in the development of metal alloy membranes for hydrogen purification in practical, chemically robust processes.

Keywords

hydrogen purificationdiffusionfilmmetal alloy
Type
Research Article
Information
MRS Bulletin , Volume 31 , Issue 10: Membranes for Hydrogen Purification: An Important Step Toward a Hydrogen-Based Economy , October 2006 , pp. 770 - 773
Copyright
Copyright © Materials Research Society 2006

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