Hostname: page-component-78c5997874-fbnjt Total loading time: 0 Render date: 2024-11-10T17:34:55.818Z Has data issue: false hasContentIssue false
  • English
  • Français

Pressure-Sensitive Adhesives: An Introductory Course

Published online by Cambridge University Press:  31 January 2011

Costantino Creton
Get access

Abstract

Self-adhesive materials are called, in the adhesives trade, “pressure-sensitive adhesives” (PSAs). PSAs are designed to stick on almost any surface by simple contact under light pressure. This special class of adhesives does not undergo any physical transformation or chemical reaction during the bonding process. Because of this, the rheological properties of the adhesive must be finely tuned for the application, combining a carefully chosen polymer architecture and monomer composition with the proper addition of small molecules called tackifying resins. PSAs are soft, deformable solids and, depending on the formulation, easily form bridging fibrils between two surfaces upon debonding. They are safe to use and easy to handle and thus are increasingly replacing more conventional types of adhesives. In this article, we review both the primary material characteristics of PSAs and the main physical principles that make them work effectively.

Keywords

acrylicsblock copolymerspeelpolymerspressure-sensitive adhesivestackifying resins
Type
Research Article
Information
MRS Bulletin , Volume 28 , Issue 6: Materials Science of Adhesives: How to Bond Things Together , June 2003 , pp. 434 - 439
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Satas, D., in Handbook of Pressure Sensitive Adhesive Technology, 2nd ed., Vol. 1, edited by Satas, D. (Van Nostrand Reinhold, New York, 1989) p. 940.CrossRefGoogle Scholar
2.Benedek, I., Pressure-Sensitive-Adhesive Formulation, 1st ed. (VSP, Utrecht, 2000).Google Scholar
3.Creton, C. and Fabre, P., in Comprehensive Adhesion Science, Vol. 1, edited by Dillard, D.A. and Pocius, A.V. (Elsevier, Amsterdam, 2002) p. 535.Google Scholar
4.Creton, C., in Processing of Polymers, 1st ed., Materials Science and Technology, Vol. 18, edited by Meijer, H.E.H. (VCH, Weinheim, 1997) p. 707.Google Scholar
5.Zosel, A., Adv. Pressure Sensitive Adhes. Technol. I (1992) p. 92.Google Scholar
6.Gay, C. and Leibler, L., Phys. Today (1999) p. 47.Google Scholar
7.Nakajima, N., Babrowicz, R., and Harrell, E.R., J. Polym. Sci., Polym. Phys. Ed. 44 (1992) p. 1437.Google Scholar
8.Kraus, G., Rollmann, K.W., and Gray, R.A., J. Adhes. 10 (1979) p. 221.CrossRefGoogle Scholar
9.Brown, K., Hooker, J.C., and Creton, C., Macromol. Mater. Eng. 287 (2002) p. 163.3.0.CO;2-P>CrossRefGoogle Scholar
10.Roos, A. and Creton, C., in Proc. 25th Annu. Meeting of the Adhesion Society (The Adhesion Society, Blacksburg, VA, 2002) p. 371.Google Scholar
11.Dahlquist, C.A., Pressure-Sensitive Adhesives, Vol. 2, edited by Patrick, R.L. (Marcel Dekker, New York, 1969) p. 219.Google Scholar
12.Gent, A.N. and Schultz, J., J. Adhes. 3 (1972) p. 281.CrossRefGoogle Scholar
13.Zosel, A., J. Adhes. 30 (1989) p. 135.CrossRefGoogle Scholar
14.Zosel, A., Colloid Polym. Sci. 263 (1985) p. 541.CrossRefGoogle Scholar
15.Lakrout, H., Sergot, P., and Creton, C., J. Adhes. 69 (1999) p. 307.CrossRefGoogle Scholar
16.Chikina, I. and Gay, C., Phys. Rev. Lett. 85 (2000) p. 4546.CrossRefGoogle Scholar
17.Creton, C. and Lakrout, H., J. Polym. Sci., Part B: Polym. Phys. 38 (2000) p. 965.3.0.CO;2-8>CrossRefGoogle Scholar
18.Crosby, A.J., Shull, K.R., Lakrout, H., and Creton, C., J. Appl. Phys. 88 (2000) p. 2956.CrossRefGoogle Scholar
19.Chiche, A., Pareige, P., and Creton, C., Compte Rend. Acad. Sci. (Paris) Sér. IV, 1 (2000) p. 1197.Google Scholar
20.Creton, C., Hooker, J.C., and Shull, K.R., Langmuir 17 (2001) p. 4948.CrossRefGoogle Scholar
21.Benyahia, L., Verdier, C., and Piau, J.M., J. Adhes. 62 (1997) p. 45.CrossRefGoogle Scholar
22.Verdier, C., Piau, J.M., and Benyahia, L., J. Adhes. 68 (1998) p. 93.CrossRefGoogle Scholar
23.Christensen, S.F., Everland, H., Hassager, O., and Almdal, K., Int. J. Adhes. Adhes. 18 (1998) p. 131.CrossRefGoogle Scholar
24.Christensen, S.F., PhD thesis, Technical University of Denmark, 1998.Google Scholar
25.Crosby, A.J. and Shull, K.R., J. Polym. Sci., Part B: Polym. Phys. 37 (1999) p. 3455.3.0.CO;2-3>CrossRefGoogle Scholar
26.Jagota, A., Hui, C.Y., Bennison, S.J., and Londono, J.D., Proc. Royal Soc. London, Series A (2003) in press.Google Scholar
27.Creton, C. and Leibler, L., J. Polym. Sci., Part B: Polym. Phys. 34 (1996) p. 545.3.0.CO;2-I>CrossRefGoogle Scholar
28.Maugis, D., J. Adhes. Sci. Technol. 10 (1996) p. 161.CrossRefGoogle Scholar
29.Ferry, J.D., Viscoelastic Properties of Polymers, 3rd ed., Vol. 1 (John Wiley & Sons, New York, 1980).Google Scholar
30.Doi, M. and Edwards, S.F., The Theory of Polymer Dynamics (Oxford University Press, New York, 1986).Google Scholar
31.Sherriff, M., Knibbs, R.W., and Langley, P.G., J. Appl. Polym. Sci. 17 (1973) p. 3438.CrossRefGoogle Scholar
32.Aubrey, D.W. and Sherriff, M., J. Polym. Sci., Polym. Chem. Ed. 16 (1978) p. 2631.Google Scholar
33.Zosel, A., J. Adhes. 34 (1991) p. 201.CrossRefGoogle Scholar
34.Kraus, G., Jones, F.B., Marrs, O.L., and Rollmann, K.W., J. Adhes. 8 (1977) p. 235.CrossRefGoogle Scholar
35.Kraus, G. and Hashimoto, T., J. Appl. Polym. Sci. 27 (1982) p. 1745.CrossRefGoogle Scholar
36.Kraus, G. and Rollmann, K.W., J. Appl. Polym. Sci. 21 (1977) p. 3311.CrossRefGoogle Scholar
37.Bates, F.S. and Frederickson, G.H., Annu. Rev. Phys. Chem. 41 (1990) p. 525.CrossRefGoogle Scholar
38.Roos, A., PhD thesis, Université Paris VI, 2003.Google Scholar
39.Aymonier, A., Papon, E., Villenave, J.-J., Tordjeman, P., Pirri, R., and Gérard, P., Chem. Mater. 13 (2001) p. 2562.CrossRefGoogle Scholar
40.Mallégol, J., Dupont, O., and Keddie, J.L., Langmuir 17 (2001) p. 7022.CrossRefGoogle Scholar
41.Amouroux, N., Petit, J., and Léger, L., Langmuir 17 (2001) p. 6510.CrossRefGoogle Scholar
42.Josse, G., Creton, C., and Dorget, M., in Proc. Euradh 2000 (Société Française du Vide, Paris, 2000) p. 165.Google Scholar
43.Zhang Newby, B.-M., Chaudhury, M.K., and Brown, H.R., Science 269 (1995) p. 1407.CrossRefGoogle Scholar
44.Karmann, W. and Zöllner, S., Eur. Adhesives & Sealants (12) (1996) p. 3.Google Scholar
45.Mallégol, J., Gorce, J.-P., Dupont, O., Jeynes, C., McDonald, P.J., and Keddie, J.L., Langmuir 18 (2002) p. 4478.CrossRefGoogle Scholar
46.Zosel, A. and Schuler, B., J. Adhes. 70 (1999) p. 179.CrossRefGoogle Scholar