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Some reflections on the current state of Cr-based polymerization catalysts

Published online by Cambridge University Press:  13 March 2013

Max McDaniel
Max McDaniel*
Affiliation:
Chevron-Phillips Chemical Company, Phillips Research Center, Bartlesville, OK; McDanMP@cpchem.com
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Abstract

The state of Phillips Cr/silica catalyst technology is discussed in this article, including recent advances in the science and also economic and environmental challenges to its continued viability. Although these catalysts have often been described as “mature,” many new innovations have been introduced in the past decade that reduce cost, improve quality, and expand the range of products that can be made. Polymers having unusually high, and low, levels of long-chain branching have been introduced. Several advances in the control of the short-chain branch distribution have also been made. Ways to lower the catalyst costs have been successfully implemented, such that Phillips-type catalysts are still the least expensive in the industry. Finally, new chromium-containing hybrid catalysts have been made that marry attributes from single-site and conventional Cr oxide catalysts.

Keywords

Crcatalyticpolymerizationporosity
Type
Research Article
Information
MRS Bulletin , Volume 38 , Issue 3: Ziegler-Natta catalysis: 50 years after the Nobel Prize , March 2013 , pp. 234 - 238
Copyright
Copyright © Materials Research Society 2013

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References

1. McDaniel, M.P., in Advances in Catalysis, Gates, B.C., Knoezinger, H., Jentoft, F.C., Eds. (Academic Press, Elsevier, NY), vol. 53, pp. 123–606.Google Scholar
2. Nenu, C.N., Groppo, E., Lamberti, C., Beale, A.M., Visser, T., Zecchina, A., Weckhuysen, B.M., Angew. Chem. Int. Ed. 46, 1465 (2007).Google Scholar
3. Groppo, E., Damin, A., Arean, C.O., Zecchina, A., Chem. Eur. J. 17, 11110 (2011).Google Scholar
4. Groppo, E., Lamberti, C., Bordiga, S., Spoto, G., Zecchina, A., Chem. Rev. 105, 115 (2005).Google Scholar
5. Groppo, E., Lamberti, C., Spoto, G., Bordiga, S., Magnacca, G., Zecchina, A., J. Catal. 236, 233 (2005).Google Scholar
6. Zecchina, A., Bertarione, S., Damin, A., Scarano, D., Lamberti, C., Prestipino, C., Spoto, G., Bordiga, S., Phys. Chem. Chem. Phys. 5, 4414 (2003).Google Scholar
7. Fang, Y., Liu, B., Hasebe, K., Terano, M., J. Polym. Sci., Part A: Polym. Chem. 43, 4632 (2005).Google Scholar
8. Fang, Y., Xia, W., He, M., Liu, B., Hasebe, K., Terano, M., J. Mol. Catal. A: Chem. 247, 240 (2006).Google Scholar
9. Xia, W., Tonosaki, K., Taniike, T., Terano, M., Fujitani, T., Liu, B., J. Appl. Polym. Sci. 111, 1869 (2009).Google Scholar
10. Ikeda, H., Monoi, T., Sasaki, Y., J. Polym. Sci., Part A: Polym. Chem. 41, 413 (2003).Google Scholar
11. Monoi, T., Ikeda, H., Sasaki, Y., Matsumoto, Y., Polym. J. 35 (7), 608 (2003).CrossRefGoogle Scholar
12. Groppo, E., Lamberti, C., Bordiga, S., Spoto, G., Zecchina, A., J. Catal. 240, 172 (2006).Google Scholar
13. Scott, S.L., Ajjou, J.A.N., Chem. Eng. Sci. 56, 4155 (2001).Google Scholar
14. Liu, B., Nakatani, H., Terano, M., J. Mol. Catal. A: Chem. 184, 387 (2002).Google Scholar
15. Zhong, L., Liu, Z., Cheng, R., Tang, S., Qiu, P., He, X., Terano, M., Liu, B., Chem. Cat. Chem. 4, 872 (2012).Google Scholar
16. Bordiga, S., Bertarione, S., Damina, A., Prestipino, C., Spoto, G., Lamberti, C., Zecchina, A., J. Mol. Catal. A: Chem. 204–205, 527 (2003).Google Scholar
17. Zecchina, A., Groppo, E., Damin, A., Prestipino, C., Top. Organomet. Chem. 16, 1 (2005).Google Scholar
18. Liu, B., Nakatani, H., Terano, M., J. Mol. Catal. A: Chem. 201, 189 (2003).Google Scholar
19. Kissin, Y.V., Brandolini, A.J., J. Polym. Sci., Part A: Polym. Chem. 46, 5330 (2008).CrossRefGoogle Scholar
20. Schwerdtfeger, E., Buck, R., McDaniel, M.P., Appl. Catal., A 423–424, 91 (2012).Google Scholar
21. Baker, L.M., Carrick, W.L., J. Org. Chem. 33 (2), 616 (1968).CrossRefGoogle Scholar
22. Liu, B., Fang, Y., Terano, M., Mol. Simul. 30 (15), 963 (2004).Google Scholar
23. Xu, X.R., Li, H.B., Li, X.Y., Gu, J.D., Chemosphere 57, 609 (2004).Google Scholar
24. McDaniel, M.P., Collins, K.S., Benham, E.A., J. Catal. 252 (2), 281 (2007).Google Scholar
25. Monoi, T., Yamamoto, M., Torigoe, H., Ishahara, Y., Inazawa, S., US Patent 6,326,443 (December 4, 2001).Google Scholar
26. McDaniel, M.P., Collins, K.S., Smith, J.L., Benham, E.A., Johnson, M.M., Eaton, A.P., Jensen, M.D., Martin, J.L., Hawley, G.R., US Patent 6,992,032, (January 31, 2006).Google Scholar
27. McDaniel, M.P., Collins, K.S., Benham, E.A., Cymbaluk, T.H., Appl. Catal., A 335 (2), 252 (2008).Google Scholar
28. Józwiak, W.K., Ignaczak, W., Dominiak, D., Maniecki, T.P., Appl. Catal., A 258, 33 (2004).Google Scholar
29. McDaniel, M.P., Collins, K.S., Benham, E.A., Cymbaluk, T.H., Appl. Catal., A 335 (2), 180 (2008).CrossRefGoogle Scholar
30. McDaniel, M.P., Welch, M.B., Dreiling, M.J., J. Catal. 82, 118 (1983).Google Scholar
31. Hogan, J.P., US Patent 3,130,188 (April 21, 1964).Google Scholar
32. Kallenbach, L.R., US Patent 3,445,367 (May 1969).Google Scholar
33. McDaniel, M.P., Welch, M.B., J. Catal. 82, 110 (1983).Google Scholar
34. McDaniel, M.P., Benham, E.A., Martin, S.J., US Patent 4,988,657 (January 29, 1991); US Patent 5,171,801 (December 15, 1992).Google Scholar
35. Barzan, C., Groppo, E., Quadrelli, E.A., Monteilb, V., Bordiga, S., Phys. Chem. Chem. Phys. 14, 2239 (2012).Google Scholar
36. McDaniel, M.P., Jensen, J.D., Jayaratne, K., Collins, K.S., Benham, E.A., McDaniel, N.D., Das, P.K., Martin, J.L., Yang, Q., Thorn, M.G., Masino, A.P., in Tailor-Made Polymers, Severn, J.R., Chadwick, J.C., Eds. (Wiley-VCH Verlag GmbH, Weinheim, Germany, 2008), Chap. 7, pp. 171–210.CrossRefGoogle Scholar
37. McDaniel, M.P., Benham, E.A., Martin, S.J., Collins, K.S., Smith, J.L., Hawley, G.R., Wittner, C.E., Jensen, M.D., US Patent 6,300,271 (October 9, 2001).Google Scholar
38. McDaniel, M.P., Collins, K.S., Johnson, M.M., Smith, J.L., Benham, E.A., Hawley, G.R., Wittner, C.E., Jensen, M.D., US Patent 6,107,230 (August 22, 2000).Google Scholar
39. McDaniel, M.P., Collins, K.S., Benham, E.A., Deslauriers, P.J., US Patent 6,214,642 (May 8, 2007).Google Scholar
40. DesLauriers, P.J., McDaniel, M.P., Rohlfing, D.C., Krishnaswamy, R.K., Secora, S.J., Benham, E.A., Maeger, P.L., Wolfe, A.R., Sukhadia, A.M., Beaulieu, W.B., Polym. Eng. Sci. 45 (9), 1203 (2005).Google Scholar
41. Hernandez Vaquero, J.L., Segura, S., Hernandez Borjabad, V., Benham, E.A., McDaniel, M.P., Seltzer, R., Frontini, P.M., Eur. Tech. J. 552, 570 (2002).Google Scholar
42. McDaniel, M.P., Collins, K.S., US Patent 8,211,988 (July 3, 2012).Google Scholar
43. McDaniel, M.P., Collins, K.S., US Patent 7,638,456 (December 29, 2009).Google Scholar
44. Chua, Y.T., Stair, P.C., Wachs, I.E., J. Phys. Chem. 105, 8600 (2001).CrossRefGoogle Scholar
45. Zecchina, A., Scarano, D., Bordiga, S., Spoto, G., Adv. Catal. 46, 265 (2001).Google Scholar
46. McDaniel, M.P., Collins, K.S., Benham, E.A., Eaton, A.P., Jensen, M.D., Martin, J.L., Hawley, G.R., Hsieh, E.T., US Patent 6,750,302 (June 15, 2004).Google Scholar
47. McDaniel, M.P., Benham, E.A., Jensen, M.D., Collins, K.S., Martin, J.L., Hawley, G.R., US Patent 7,163,906 (January 16, 2007).Google Scholar
48. DesLauriers, P.J., McDaniel, M.P., J. Polym. Sci. 45 (15), 3135 (2007).Google Scholar
49. Hogan, J.P., Levett, C.T., Werkman, R.T., SPE J. 23 (11), 87 (1967).Google Scholar
50. McDaniel, M.P., Rohlfing, D.C., Benham, E.A., Polym. React. Eng. 11 (2), 101 (2003).Google Scholar
51. Yu, Y., Schwerdtfeger, E.D., McDaniel, M.P., J. Polym. Sci., Part A: Polym. Chem. 50, 1166 (2012).CrossRefGoogle Scholar
52. Yang, Q., Jensen, M.D., McDaniel, M.P., Macromolecules 43, 8836 (2010).Google Scholar
53. Hogan, J.P., Kitchen, A.G., US Patent 3,225,023 (December 21, 1965).Google Scholar
54. Dietz, R.E., US Patent 3,887,494 (June 3, 1975).Google Scholar
55. Baricordi, A., US Patent 3,119,569 (January 28, 1964).Google Scholar
56. Hogan, J.P., Norwood, D.D., US Patent 4,053,436 (October 11, 1977).Google Scholar
57. McDaniel, M.P., ACS Catal. 1, 1394 (2011).Google Scholar
58. McDaniel, M.P., Collins, K.S., J. Catal. 261, 34 (2009).Google Scholar
59. McDaniel, M.P., Collins, K.S., J. Polym. Sci., Part 1: Chem. 47 (3), 845 (2009).Google Scholar
60. Shveima, J.S., McDaniel, M.P., Martin, S.J., Collins, K.S., Benham, E.A., Eaton, A.P., Sukhadia, A.M, US Patent 6,538,077 (November 1999); US Patent 6,716,938 (April 2004).Google Scholar
61. McGuinness, D.S., Chem. Rev. 111 (3), 2321 (2011).Google Scholar
62. Reagen, W.K., Conroy, B.K., US Patent 5,198,563 (March 30, 1993).Google Scholar
63. Reagen, W.K., McDaniel, M.P., US Patent 5,382,738 (January 17, 1995).Google Scholar
64. Reagen, W.K., Pettijohn, T.M., Martin, S.J., US Patent 5,331,070 (July 19, 1994).Google Scholar
65. Reagen, R.K., Pettijohn, T.M., Freeman, J.W., US Patent 5,523,507 (June 4, 1996).Google Scholar
66. Benham, E.A., Smith, P.D., McDaniel, M.P., Polym. Eng. Sci. (SPE) 28 (22), 1469 (1988).Google Scholar
67. Benham, E.A., Smith, P.D., Hsieh, E.T., McDaniel, M.P., J. Macromol. Sci., Chem. A 25 (3), 259 (1988).Google Scholar
68. Dixon, J.T., Green, M.J., Hess, F.M., Morgan, D.H., J. Organomet. Chem. 689, 3641 (2004).Google Scholar
69. Bollmann, A., Blann, K., Dixon, J.T., Hess, F.M., Killian, E., Maumela, H., McGuinness, D.S., Morgan, D.H., Neveling, A., Otto, S., Overett, M., Slawin, A.M.Z., Wasserscheid, P., Kuhlmann, S., J. Am. Chem. Soc. 126, 14712 (2004).Google Scholar
70. Blann, K., Bollmann, A., Dixon, J.T., Neveling, A., Morgan, D.H, Maumela, H., Killian, E., Hess, F., Otto, S., Pepler, L., Mahomed, H., Overett, M., WO Patent 04056479A1 (Sasol Technology, 2004).Google Scholar
71. Beaulieu, W.B., SPI Conference, Film and Packaging (Dallas, TX, May 2012).Google Scholar