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Advanced cathode materials for lithium-ion batteries

Published online by Cambridge University Press:  14 July 2011

Zonghai Chen ,
Dong-Ju Lee ,
Yang-Kook Sun  and
Khalil Amine
Zonghai Chen
Affiliation:
Argonne National Laboratory, Argonne, IL 60439, USA; zonghai.chen@anl.gov
Dong-Ju Lee
Affiliation:
Hanyang University, Seoul 133-791, Republic of Korea; 2dongju@gmail.com
Yang-Kook Sun
Affiliation:
Hanyang University, Seoul 133-791, Republic of Korea; yksun@hanyang.ac.kr
Khalil Amine
Affiliation:
Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, IL 60439, USA; amine@anl.gov
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Abstract

High-energy cathode materials with high working potential and/or high specific capacity are desired for future electrification of vehicles. In this article, we provide a general overview of advanced high-energy cathode materials using different approaches such as core-shell, concentration-gradient materials, and the effects of nanocoatings at the particle level to improve both electrochemical performance and safety. We also summarize the methods used to prepare these materials. Special attention is placed on the co-precipitation process for making dense, spherical particles for the purpose of improving the powder packing density and increasing the electrode energy density.

Keywords

Energy storagebarrier layercoatingcore/shellnanostructure
Type
Research Article
Information
MRS Bulletin , Volume 36 , Issue 7: Electrochemical energy storage to power the 21st century , July 2011 , pp. 498 - 505
Copyright
Copyright © Materials Research Society 2011

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