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Characterization and nanopatterning of organically functionalized graphene with ultrahigh vacuum scanning tunneling microscopy

Published online by Cambridge University Press:  14 July 2011

Qing Hua Wang  and
Mark C. Hersam
Qing Hua Wang
Affiliation:
Massachusetts Institute of Technology, Cambridge, MA 02139, USA; qhwang@mit.edu
Mark C. Hersam
Affiliation:
Materials Science and Engineering, Northwestern University, Evanston, IL 60208-3108 USA; m-hersam@northwestern.edu
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Abstract

With exceptional carrier mobilities, mechanical strength, and optical transparency, graphene is a leading material for next-generation electronic devices. However, for most applications, graphene will need to be integrated with other materials, which motivates efforts to understand and tune its surface chemistry. In particular, the modification of graphene via organic functionalization holds promise for tuning the electronic properties of graphene, controlling interfaces with other materials, and tailoring surface chemical reactivity. Toward these ends, this article reviews recent work from our laboratory on noncovalent and covalent organic functionalization of graphene. Using ultrahigh vacuum scanning tunneling microscopy (UHV STM), the molecular ordering and electronic properties of organic adlayers on graphene are characterized at the molecular scale. In addition, UHV STM is employed to nanopattern these organic layers with sub-5 nm resolution, thus providing a pathway for producing graphene-based heteromolecular nanostructures.

Keywords

Nanoscalesurface chemistryelectronic structureself-assemblyscanning tunneling microscopy
Type
Research Article
Information
MRS Bulletin , Volume 36 , Issue 7: Electrochemical energy storage to power the 21st century , July 2011 , pp. 532 - 542
Copyright
Copyright © Materials Research Society 2011

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