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Emerging operando and x-ray pair distribution function methods for energy materials development

Published online by Cambridge University Press:  14 March 2016

Karena W. Chapman
Karena W. Chapman*
Affiliation:
Argonne National Laboratory, USA; chapmank@aps.anl.gov
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Abstract

Our energy needs drive widespread materials research. Advances in materials characterization are critical to this research effort. Using new characterization tools that allow us to probe the atomic structure of energy materials in situ as they operate, we can identify how their structure is linked to their functional properties and performance. These fundamental insights serve as a roadmap to enhance performance in the next generation of advanced materials. In the last decade, developments in synchrotron instrumentation have made the pair distribution function (PDF) method and operando x-ray studies more readily accessible tools capable of providing valuable insights into complex materials systems. Here, the emergence of the PDF method as a versatile structure characterization tool and the further enhancement of this method through developments in operando capabilities and multivariate data analytics are described. These advances in materials characterization are demonstrated by several highlighted studies focused on energy storage in batteries.

Keywords

nanostructurecrystallographic structurex-ray diffraction (XRD)energy storageamorphous
Type
Research Article
Information
MRS Bulletin , Volume 41 , Issue 3: Metamorphic Epitaxial Materials , March 2016 , pp. 231 - 240
Copyright
Copyright © Materials Research Society 2016 

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