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Inside out—Visualizing dynamic chemical transformations in situ with nanometer-scale resolution

Published online by Cambridge University Press:  10 October 2017

Jennifer A. Dionne
Jennifer A. Dionne*
Affiliation:
Stanford University, USA; jdionne@stanford.edu
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Abstract

In Pixar’s Inside Out, the character Joy proclaims, “Do you ever look at someone and wonder what’s going on inside?” Driven by similar curiosity, the scientific community has developed remarkable in situ characterization tools to visualize the inner workings of complex, dynamic systems, elucidating their functions and enabling next-generation technologies. This article describes our research developing plasmonic techniques to visualize dynamic chemical transformations in situ with nanometer-scale resolution. As a model system, we investigated the hydrogenation and dehydrogenation of palladium nanocrystals. Using environmental electron microscopy and spectroscopy, we monitored this reaction with sub-2-nm spatial resolution and millisecond time resolution. Particles of different sizes, shapes, and crystallinities exhibit distinct thermodynamic and kinetic properties, highlighting several important design principles for next-generation catalysts and energy-storage devices.

Keywords

nanostructureenergy storagetransmission electron microscopyelectron energy loss spectroscopy
Type
Research Article
Information
MRS Bulletin , Volume 42 , Issue 10: Materials Under Pressure , October 2017 , pp. 743 - 751
Copyright
Copyright © Materials Research Society 2017 

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