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Transition metal-catalyzed polymerization of polar allyl and diallyl monomers

Published online by Cambridge University Press:  13 March 2013

Daisuke Takeuchi
Daisuke Takeuchi*
Affiliation:
Chemical Resources Laboratory, Tokyo Institute of Technology, Japan; dtakeuch@res.titech.ac.jp
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Abstract

Recent advances in polymerization of allyl and diallyl monomers catalyzed by homogeneous Ziegler-Natta catalysts are reviewed. Zirconocene catalysts are effective for copolymerization of ethylene or propylene with Al-masked allyl monomers, as well as homopolymerization of allylsilanes. Phosphine-sulfonate Pd complexes promote the copolymerization of ethylene with various polar allyl monomers, in the absence of a masking agent. Late transition metal catalysts promote stereoselective cyclopolymerization of diallyl monomers having various polar functional groups. The cyclopolymerization of alkyl-substituted diallyl monomers by Pd diimine complexes affords the polymer having alternating oligomethylene and trans-1,2-cyclopentene groups.

Keywords

OrganometallicCatalyticPolymerization
Type
Research Article
Information
MRS Bulletin , Volume 38 , Issue 3: Ziegler-Natta catalysis: 50 years after the Nobel Prize , March 2013 , pp. 252 - 259
Copyright
Copyright © Materials Research Society 2013

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