Hostname: page-component-cd9895bd7-gbm5v Total loading time: 0 Render date: 2024-12-28T22:13:42.907Z Has data issue: false hasContentIssue false
  • English
  • Français

Ziegler-Natta catalysis: Forever young

Published online by Cambridge University Press:  13 March 2013

Vincenzo Busico
Vincenzo Busico*
Affiliation:
Dipartimento di Scienze Chimiche, Università di Napoli Federico II, Italy; busico@unina.it
Get access

Abstract

The future of polyolefin-based materials and the opportunities for further research and development in Ziegler-Natta catalysis are discussed. Thorough control of polymer microstructure and architecture ensured by modern olefin polymerization catalysts and processes warrants further progress in fundamental and applied research for many years to come.

Keywords

olymerizationcatalyticorganometallic
Type
Research Article
Information
MRS Bulletin , Volume 38 , Issue 3: Ziegler-Natta catalysis: 50 years after the Nobel Prize , March 2013 , pp. 224 - 228
Copyright
Copyright © Materials Research Society 2013

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Severn, J.R., Chadwick, J.C., Eds., Tailor-Made Polymers via Immobilization of Alpha-Olefin Polymerization Catalysts (Wiley-VCH, Weinheim, 2008).Google Scholar
2. Busico, V., Cipullo, R., Prog. Polym. Sci. 26, 443 (2001).Google Scholar
3. Moore, E.P. Jr., Ed., Polypropylene Handbook (Hanser-Gardner Publications, Cincinnati, OH, 1996).Google Scholar
4. Press, K., Cohen, A., Goldberg, I., Venditto, V., Mazzeo, M., Kol, M., Angew. Chem. Int. Ed. 50, 1 (2011).Google Scholar
5. Schoebel, A., Herdtweck, E., Parkinson, M., Rieger, B., Chem. Eur. J. 18, 4174 (2012).Google Scholar
6. Gahleitner, M., Jääskeläinen, P., Ratajski, E., Paulik, C., Reussner, J., Wolfschwenger, J., Neißl, W., J. Appl. Polym. Sci. 95, 1073 (2005).CrossRefGoogle Scholar
7. Nomura, K., Dalton Trans. 41, 8811 (2009).Google Scholar
8. Boor, J. Jr., Ziegler-Natta Catalysts and Polymerizations (Academic Press, New York, NY, 1979).Google Scholar
9. Andresen, A., Cordes, H.G., Herwig, H., Kaminsky, W., Merk, A., Mottweiler, R., Pein, J., Sinn, H., Vollmer, H.J., Angew. Chem. Int. Ed. 15, 630 (1976).CrossRefGoogle Scholar
10. Ewen, J.A., J. Am. Chem. Soc. 106, 6355 (1984).CrossRefGoogle Scholar
11. Wild, F., Zsolnai, L., Huttner, G., Brintzinger, H.-H., J. Organomet. Chem. 232, 233 (1982).Google Scholar
12. Kaminsky, W., Külper, K., Brintzinger, H.-H., Wild, F., Angew. Chem. Int. Ed. 24, 507 (1985).Google Scholar
13. Resconi, L., Cavallo, L., Fait, A., Piemontesi, F., Chem. Rev. 100, 1253 (2000).Google Scholar
14. Britovsek, G.J.P., Gibson, V.C., Wass, D.F., Angew. Chem. Int. Ed. 38, 428 (1999).3.0.CO;2-3>CrossRefGoogle Scholar
15. Gibson, V.C., Spitzmesser, S.K., Chem. Rev. 103, 283 (2003).Google Scholar
16. Frazier, K.A., Boone, H.W., Vosejpka, P.C., Stevens, J.C., US Patent 6,953,764 (2005).Google Scholar
17. Boussie, T.R., Brummer, O., Diamond, G.M., Goh, C., LaPointe, A.M., Leclerc, M.K., Shoemaker, J.A.W., US Patent 6,841,502 (2005).Google Scholar
18. Busico, V., Cipullo, R., Pellecchia, R., Ronca, S., Roviello, G., Talarico, G., Proc. Natl. Acad. Sci. 103, 15321 (2006).CrossRefGoogle Scholar
19. Makio, H., Fujita, T., Acc. Chem. Res. 42, 1532 (2009).Google Scholar
20. Kol, M., Press, K., Cohen, A., WO 158241 (A1) (2011).Google Scholar
21. Coates, G.W., Hustad, P.D., Reinartz, S., Angew. Chem. Int. Ed. 41, 2236 (2002).Google Scholar
22. Busico, V., Cipullo, R., Friederichs, N., Ronca, S., Talarico, G., Togrou, M., Wang, B., Macromolecules 37, 8201 (2004).Google Scholar
23. Busico, V., Talarico, G., Cipullo, R., Macromol. Symp. 226, 1 (2005).Google Scholar
24. Domski, G.J., Rose, J.M., Coates, G.W., Bolig, A.D., Brookhart, M., Prog. Polym. Sci. 32, 30 (2007).Google Scholar
25. Deplace, F., Scholz, A.K., Fredrickson, G.H., Kramer, E.J., Shin, Y.-W., Shimizu, F., Zuo, F., Rong, L., Hsiao, B.S., Coates, G.W., Macromolecules 45, 5604 (2012).Google Scholar
26. Arriola, D.J., Carnahan, E.M., Hustad, P.D., Kuhlman, R.L., Wenzel, T.T., Science 312, 714 (2006).Google Scholar
27. Hustad, P.D., Kuhlman, R.L., Arriola, D.J., Carnahan, E.M., Wenzel, T.T., Macromolecules 40, 7061 (2007).CrossRefGoogle Scholar
28. Natta, G., J. Polym. Sci. 34, 531 (1959).Google Scholar
29. Hustad, P.D., Science 325, 704 (2009).Google Scholar
30. Ewen, J.A., Sci. Am. 5, 86 (1997).Google Scholar
31. Boussie, T.R., Diamond, G.M., Goh, C., Hall, K.A., LaPointe, A.M., Leclerc, M.K., Murphy, V., Shoemaker, J.A.W., Turner, H., Rosen, R.K., Stevens, J.C., Alfano, F., Busico, V., Cipullo, R., Talarico, G., Angew. Chem. Int. Ed. 45, 3278 (2006).CrossRefGoogle Scholar
32. Froese, R.D.J., Hustad, P.D., Kuhlman, R.L., Wenzel, T.T., J. Am. Chem. Soc. 129, 7831 (2007).Google Scholar
33. Zuccaccia, C., Macchioni, A., Busico, V., Cipullo, R., Talarico, G., Alfano, F., Boone, H.W., Frazier, K.A., Hustad, P.D., Stevens, J.C., Vosejpka, P.C., Abboud, K.A., J. Am. Chem. Soc. 130, 10354 (2008).CrossRefGoogle Scholar
34. Zuccaccia, C., Busico, V., Cipullo, R., Talarico, G., Froese, R.D.J., Vosejpka, P.C., Hustad, P.D., Macchioni, A., Organometallics 28, 5445 (2009).Google Scholar
35. Busico, V., Cipullo, R., Pellecchia, R., Rongo, L., Talarico, G., Macchioni, A., Zuccaccia, C., Froese, R.D.J., Hustad, P.D., Macromolecules 42, 4369 (2009).CrossRefGoogle Scholar
36. Cecchin, G., Morini, G., Pelliconi, A., Macromol. Symp. 173, 195 (2001).Google Scholar
37. Simonazzi, T., Cecchin, G., Mazzullo, S., Prog. Polym. Sci. 16, 303 (1991).Google Scholar
38. Mei, G., Herben, P., Cagnani, C., Mazzucco, A., Macromol. Symp. 245–246, 677 (2006).Google Scholar
39. Gahleitner, M., Prog. Polym. Sci. 26, 895 (2001).Google Scholar
40. Busico, V., Dalton Trans. 41, 8794 (2009).Google Scholar
41. Hustad, P.D., Marchand, G.R., Garcia-Meitin, E.I., Roberts, P.L., Weinhold, J.D., Macromolecules 42, 3788 (2009).Google Scholar
42. Hagemeyer, A., Strasser, P., Volpe, A.F. Jr., Eds., High Throughput Screening in Catalysis (Wiley-VCH, Weinheim, 2004).Google Scholar
43. Peil, K.P., Neithamer, D.R., Patrick, D.W., Wilson, B.E., Tucker, C.J., Macromol. Rapid Commun. 25, 119 (2004).CrossRefGoogle Scholar
44. Chum, P.S., Swogger, K.W., Prog. Polym. Sci. 33, 797 (2008).CrossRefGoogle Scholar
45. Busico, V., Pellecchia, R., Cutillo, F., Cipullo, R., Macromol. Rapid Commun. 30, 1697 (2009).CrossRefGoogle Scholar
46. www.freeslate.com/applications/chemicals-energy/polyolefins-polymers/rapid-gpc (accessed August 14, 2012).Google Scholar
47. www.polymerchar.com/cef (accessed August 14, 2012).Google Scholar
48. Zhou, Z., Kümmerle, R., Stevens, J.C., Redwine, D., He, Y., Qiu, X., Cong, R., Klosin, J., Montañez, N., Roof, G., J. Magn. Reson. 200, 328 (2009).Google Scholar
49. Zhou, Z., Stevens, J.C., Klosin, J., Kümmerle, R., Qiu, X., Redwine, D., Cong, R., Taha, A., Mason, J., Winniford, B., Chauvel, P., Montañez, N., Macromolecules 42, 2291 (2009).Google Scholar
50. Srebro, M., Michalak, A., in Handbook of Transition Metal Polymerization Catalysis, Hoff, R., Mathers, R.T., Eds. (Wiley, Hoboken, NJ, 2010).Google Scholar
51. Busico, V., Causà, M., Cipullo, R., Credendino, R., Cutillo, F., Friederichs, N., Lamanna, R., Segre, A., Van Axel Castelli, V., J. Phys. Chem. C 112, 1081 (2008).Google Scholar
52. Credendino, R., Busico, V., Causà, M., Barone, V., Budzelaar, P.H.M., Zicovich-Wilson, C., Phys. Chem. Chem. Phys. 11, 11264 (2009).CrossRefGoogle Scholar
53. D’Amore, M., Credendino, R., Budzelaar, P.H.M., Causá, M., Busico, V., J. Catal. 286, 103 (2012).Google Scholar
54. Ciancaleoni, G., Fraldi, N., Budzelaar, P.H.M., Busico, V., Cipullo, R., Macchioni, A., J. Am. Chem. Soc. 132, 13651 (2010).CrossRefGoogle Scholar
55. Ciancaleoni, G., Fraldi, N., Budzelaar, P.H.M., Busico, V., Macchioni, A., Organometallics 30, 3096 (2011).CrossRefGoogle Scholar
56. Ciancaleoni, G., Fraldi, N., Cipullo, R., Busico, V., Macchioni, A., Budzelaar, P.H.M., Macromolecules 45, 4046 (2012).Google Scholar
57. Yang, Q., Jensen, M.D., McDaniel, M.P., Macromolecules 43, 8836 (2010).Google Scholar
58. Budzelaar, P.H.M., Wiley Interdiscip. Rev., Comput. Mol. Sci. 2, 221 (2012).Google Scholar
59. Corradini, P., Guerra, G., Cavallo, L., Acc. Chem. Res. 37, 231 (2004).Google Scholar
60. Scordamaglia, R., Barino, L., Macromol. Theory Simul. 7, 399 (1998).Google Scholar
61. Andoni, A., Chadwick, J.C., Niemantsverdriet, H.J.W., Thüne, P.C., J. Catal. 257, 81 (2008).Google Scholar
62. Cheruvathur, A.V., Langner, E.H.G., Niemantsverdriet, J.W. (Hans), Thüne, P.C., Langmuir 28, 2643 (2012).Google Scholar
63. Credendino, R., Pater, J.T.M., Correa, A., Morini, G., Cavallo, L., J. Phys. Chem. C 115, 13322 (2011).Google Scholar
64. Kaminsky, W., Funck, A., Hähnsen, H., Dalton Trans. 41, 8803 (2009).Google Scholar