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PdAg-decorated three-dimensional reduced graphene oxide-multi-walled carbon nanotube hierarchical nanostructures for high-performance hydrogen peroxide sensing

Published online by Cambridge University Press:  11 May 2018

Aytekin Uzunoglu Open the ORCID record for Aytekin Uzunoglu [Opens in a new window] ,
Dursun Ali Kose ,
Kazim Kose ,
Ebru Gokmese  and
Faruk Gokmese
Aytekin Uzunoglu*
Affiliation:
Metallurgical and Materials Engineering, Faculty of Engineering and Architecture, Necmettin Erbakan University, Konya, Turkey Alaca Avni Celik Vocational School, Hitit University, Corum, Turkey
Dursun Ali Kose
Affiliation:
Department of Chemistry, Faculty of Science and Literature, Hitit University, Corum, Turkey
Kazim Kose
Affiliation:
Alaca Avni Celik Vocational School, Hitit University, Corum, Turkey
Ebru Gokmese
Affiliation:
Department of Chemistry, Faculty of Science and Literature, Hitit University, Corum, Turkey
Faruk Gokmese
Affiliation:
Department of Chemistry, Faculty of Science and Literature, Hitit University, Corum, Turkey
*
Address all correspondence to Aytekin Uzunoglu at auzunoglu@konya.edu.tr, aytekingyte@gmail.com
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Abstract

High-performance electrochemical hydrogen peroxide (H2O2) sensors based on PdAg nanoparticle-decorated reduced graphene oxide (rGO) and multi-walled carbon nanotube (MWCNT) hybrids were developed. The nanostructures were characterized using transmission electron microscopy, scanning electron microscopy, energy-dispersive spectroscopy, thermogravimetric analysis, Fourier transform spectroscopy, and x-ray diffraction techniques. It was found that introduction of MWCNT in the catalyst layer improved the sensitivity and widened the linear range. Sensitivities of 393.2, 437.1, and 576.6 µA/mM/cm2 were obtained for PdAg/rGO–MWCNT (2:1), PdAg/rGO–MWCNT (1:1), and PdAg/rGO–MWCNT (1:2), respectively. Furthermore, hierarchical structure of rGO–MWCNT nanohybrids enabled the detection of H2O2 up to 80 mM.

Type
2D Nanomaterials for Healthcare and Lab-on-a-Chip Devices Research Letters
Information
MRS Communications , Volume 8 , Issue 3 , September 2018 , pp. 680 - 686
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Copyright
Copyright © Materials Research Society 2018 

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