Published online by Cambridge University Press: 25 February 2011
The interactions between Ni and Ni/In/Ni thin-films and GaAs were studied by SEM, SAM and AES. The presence of a molten phase was observed for both contacts after annealing at 820°C for 3 minutes. This behavior was rationalized in terms of the presence of a ternary eutectic reaction in the gallium-nickel-arsenic system. DTA confirmed the existence of the reaction:
at 810°C. In the case of Ni/In/Ni, melting was thought to occur because of the segregation of indium metal to the contact surface and the subsequent melting of the nearly ternary interfacial region. Upon further cooling the formation of NiGa, NiAs, InxGa1−xAs and an unspecified compound Ni-In was believed to occur. The contact was shown to be either sintered or alloyed, depending upon processing conditions.