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Published online by Cambridge University Press: 10 February 2011
Plasma-enhanced chemical vapor deposition (PECVD) silicon nitride films deposited on both GaAs and Si substrates have been characterized by spectroscopic ellipsometry. The results indicate that such films consist of three constituents: Si3N4, voids, and amorphous silicon (α-Si). In addition, it is also observed that for typical deposition conditions there is an intervening layer of α-Si (on the order of 50–100 Å) between the nitride film and the semiconductor substrate. The thickness of this a-Si layer is found to depend on both the stoichiometry and the growth time of the nitride layer, leading to the conclusion that it is a result of excess Si diffusing from the growth surface through the nitride layer.