Hostname: page-component-6bf8c574d5-8gtf8 Total loading time: 0 Render date: 2025-02-22T16:58:59.807Z Has data issue: false hasContentIssue false
  • English
  • Français

Characterization of Proton Conducting Antimonic Acids with Amorphous, Cubic and Monoclinic Structures

Published online by Cambridge University Press:  15 February 2011

Y. Sakka ,
K. Sodeyama ,
T. Uchikoshi ,
K. Ozawa  and
M. Amano
Y. Sakka
Affiliation:
National Research Institute for Metals, 1–2–1, Sengen, Tsukuba, Ibaraki 305, Japan
K. Sodeyama
Affiliation:
Kagoshima Preferectural Institute of Industrial Technology, Oda, Kagoshima 899–51, Japan
T. Uchikoshi
Affiliation:
National Research Institute for Metals, 1–2–1, Sengen, Tsukuba, Ibaraki 305, Japan
K. Ozawa
Affiliation:
National Research Institute for Metals, 1–2–1, Sengen, Tsukuba, Ibaraki 305, Japan
M. Amano
Affiliation:
National Research Institute for Metals, 1–2–1, Sengen, Tsukuba, Ibaraki 305, Japan
Get access

Abstract

Powders and films of amorphous, cubic and monoclinic antimonic acids are prepared. Their water sorptioh isotherms and the water desorption spectra are measured. The protonie conductivities are very sensitive to water vapor pressure and are discussed with the amount of water. The amorphous and cubic antimonic acids contain larger amounts of water than the monoclinic acid, which can be attributed to the existence of micropores in the structures.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 453: Symposium R – Solid State Chemistry of Inorganic Materials , 1996 , 629
Copyright
Copyright © Materials Research Society 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Chitrakar, R. and Abe, M., Mat. Res. Bull, 23, 1231 (1988).Google Scholar
2. Kanzaki, Y., Chitrakar, R., Ohsaka, T. and Abe, M., Chem. Soc. Jpn., 1993, 1299 (1993).Google Scholar
3. England, W. A., Cross, M. G., Hamnett, A., Wiseman, P. J. and Goodenough, J. B., Solid State Ionics, 1, 231 (1980).Google Scholar
4. Chowdhry, U., Barkley, J. R., English, A. D., Sleight, A. W., Mat. Res. Bull, 17, 917 (1982).Google Scholar
5. Miura, N., Ozawa, Y. and Yamazoe, N., Chem. Soc. Jpn., 1988, 1954 (1988).Google Scholar
6. Uchikoshi, T., Sakka, Y. and Amano, M., Solid State Ionics, 89, 351 (1996).Google Scholar
7. Kobayashi, M., Nakamura, H., Kasahara, A. and Amano, M., Shigen-to-Sozai, 111, 949 (1995).Google Scholar
8. Ozawa, K., Sakka, Y. and Amano, M., J. Ceram. Soc. Jpn., 104, 756 (1996).Google Scholar
9. Sakka, Y., Sodeyama, K., Uchikoshi, T., Ozawa, K. and Amano, M., J. Am. Ceram. Soc., 79, 1677 (1996).Google Scholar
10. Dubinin, M. M., Carbon, 27, 457 (1989).Google Scholar
11. Gregg, S. J. and Sing, K. S. W., “Adsorption, Surface Area and Porosity, Second Edition”; pp.195–247, Academic Press, London, 1981.Google Scholar
12. Goodenough, J. B., “Skeleton Structures” pp. 393–415 in Solid Electrolytes, Academic Press, New York, 1978.Google Scholar
13. Kanzaki, Y., Chikrakar, R. and Abe, M., J. Phys. Chem. 94, 2206 (1990).Google Scholar