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Charge Transfer and Bond Lengths in YBa2Cu3−xMxO6+y

Published online by Cambridge University Press:  21 February 2011

P. F. Miceli ,
J. M. Tarascon ,
L. H. Greene ,
P. Barboux ,
J. D. Jorgensen ,
J. J. Rhyne  and
D. A. Neumann
P. F. Miceli
Affiliation:
Bellcore, Red Bank NJ 07701
J. M. Tarascon
Affiliation:
Bellcore, Red Bank NJ 07701
L. H. Greene
Affiliation:
Bellcore, Red Bank NJ 07701
P. Barboux
Affiliation:
Bellcore, Red Bank NJ 07701
J. D. Jorgensen
Affiliation:
Argonne National Laboratory, Argonne IL 60439
J. J. Rhyne
Affiliation:
National Institute of Standards and Technology, Gaithersburg MD 20899
D. A. Neumann
Affiliation:
National Institute of Standards and Technology, Gaithersburg MD 20899
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Abstract

We discuss the effects of doping on the Cu chain sites in YBa2Cu3−xMxO6+y. The relationship between bond lengths obtained from neutron scattering and charge transfer is evaluated in terms of bond valence. In particular, it is concluded that removing an oxygen from the chains transfers one electron to the planes.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 156: Symposium M – High Temperature Superconductors: Relationships Between Properties, Structure, and Solid State Chemistry , 1989 , 119
Copyright
Copyright © Materials Research Society 1989

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References

REFERENCES

1. Xiao, G., Streitz, F. H., Gavrin, A., Du, Y. W. and Chien, C. L., Phys. Rev. B 35, 8782 (1987).Google Scholar
2. Maeno, Y., Tomita, T., Kyogoku, M., Awaji, S., Oki, Y. A., Hoshino, K., Miniami, A. A. and Fujita, T., Nature 328, 512 (1987).Google Scholar
3. Tarascon, J. M., Barboux, P., Miceli, P. F., Greene, L. H., Hull, G. W., Eibschutz, M. and Sunshine, S., Phys. Rev. B 37, 7458 (1988).Google Scholar
4. Miceli, P. F., Tarascon, J. M., Greene, L. H., Barboux, P., Rotella, F. J. and Jorgensen, J. D., Phys. Rev. B 37, 5932 (1988).Google Scholar
5. Siegrist, T., Schneemeyer, L. F., Waszczak, J. V., Singh, N. P., Opila, R. L., Batlogg, B., Rupp, L. W. and Murphy, D. W., Phys. Rev. B 36, 8365 (1987).Google Scholar
6. Tao, Y. K., Swinnea, J. S., Manthiram, A., Kim, J. S., Goodenough, J. B. and Steinfink, H., J. Mater. Res. 3, 248 (1988).Google Scholar
7. Bordet, P., Hodeau, J. L., Strobel, P., Mareziao, M. and Santoro, A., Solid State Comm. 66, 435 (1988).Google Scholar
8. Roth, G., Heger, G., Renker, B., Pannetier, J., Caignaert, V., Hervieu, M. and Raveau, B., Physica C 153–155, 972 (1988).Google Scholar
9. Howland, R. S., Geballe, T. H., Laderman, S. S., Fischer-Colbrie, A., Scott, M. S., Tarascon, J. M. and Barboux, P., submitted to Phys. Rev. B 1989.Google Scholar
10. Xiao, G., Cieplak, M. Z., Musser, D., Gavrin, A., Streitz, F. H., Chien, C. L., Rhyne, J. J. and Gotaas, J. A., Nature 332, 238 (1988).Google Scholar
11. Kajitani, T., Kusaba, K., Kikuchi, M., Syono, Y. and Hirabayashi, M., Jpn. J. Appl. Phys. 27, L354 (1988).Google Scholar
12. Tarascon, J. M., Greene, L. H., Barboux, P., McKinnon, W. R., Hull, G. W., Orlando, T. P., Delin, K. A., Foner, S. and McNiff, E. J., Phys. Rev. B 36, 8393 (1987).Google Scholar
13. Xiao, G., Bakhshai, A., Cieplak, M. Z., Tesanovic, Z. and Chien, C. L., Phys. Rev. B 39, 315 (1989).Google Scholar
14. Johnston, D. C., Jacobsen, A. J., Newsam, J. M., Lewandowski, J. T., Goshorn, D. P., Xie, D. and Yelon, W. B., in Chemistry of High Temperature Superconductors, ed. by Nelson, D. L., Wittingham, M. S. and George, T. F. (American Chemical Society, Washington, DC, 1987), p. 136.Google Scholar
15. Kajitani, T., Kusaba, K., Kikuchi, M., Syono, Y. and Hirabayashi, M., Jpn. J. Appl. Phys. 26, L1727 (1987).Google Scholar
16. Miceli, P. F., unpublished.Google Scholar
17. Brown, I. D. and Wu, K. K., Acta Crystallogr. B 32, 1957 (1976).Google Scholar
18. Chaillout, C., Alario-Franco, M. A., Capponi, J. J., Chenavas, J., Strobel, P. and Marezio, M., Solid State Comm. 65, 283 (1988).Google Scholar
19. Jorgensen, J. D., unpublished.Google Scholar
20. Tranquada, J. M., Heald, S. M., Moodenbaugh, A. R. and Xu, Y., Phys. Rev. B 38, 8893 (1988).Google Scholar
21. Uemura, Y. J., et. al., Phys. Rev. B 38, 909 (1988).Google Scholar
22. Miceli, P. F., Tarascon, J. M., Greene, L. H., Barboux, P., Giroud, M., Neumann, D. A., Rhyne, J. J., Schneemeyer, L. F. and Waszczak, J. V., Phys. Rev. B 38, 9209 (1988).Google Scholar
23. Miceli, P. F., Tarascon, J. M., Barboux, P., Greene, L. H., Bagley, B. G., Hull, G. W., Giroud, M., Rhyne, J. J. and Neumann, D. A., Phys. Rev. B 39, (1989), in press.Google Scholar
24. Miceli, P. F., Tarascon, J. M., Bagley, B. G., Greene, L. H., Barboux, P., Hull, G. W., Giroud, M., Rhyne, J. J. and Neumann, D. A., Proc. X Winter Meeting on Low Temperature Physics (World Scientific Publishing, 1989) in press.Google Scholar