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Published online by Cambridge University Press: 15 February 2011
Using a scanning tunneling microscope in UHV we have observed anomalous superstructures on highly oriented pyrolytic graphite. We found such structures on three different samples, with hexagonal symmetry in each case but with different lattice constants of 1.7 nm, 3.8 nm and 6.6 nm. These giant lattices can be explained by assuming that the top layer of graphite is slightly rotated. This produces a hexagonal modulation of the electron state density in the first layer. Lattice points in the giant lattice are characterized by high local density of states at the Fermi level. We find that adsorbed cobalt particles occupy the top sites of the giant lattice.