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Effects of Cation Substitution on the Thermoelectric Properties in Ca-Co-O

Published online by Cambridge University Press:  21 March 2011

Ichiro Matsubara ,
Ryoji Funahashi ,
Masahiro Shikano ,
Kei Sasaki  and
Hiroyuki Enomoto
Ichiro Matsubara
Affiliation:
National Institute of Advanced Industrial Science and Technology, Ikeda, Osaka 563-8577, JAPAN
Ryoji Funahashi
Affiliation:
National Institute of Advanced Industrial Science and Technology, Ikeda, Osaka 563-8577, JAPAN
Masahiro Shikano
Affiliation:
National Institute of Advanced Industrial Science and Technology, Ikeda, Osaka 563-8577, JAPAN
Kei Sasaki
Affiliation:
Osaka Electro-Communication University, Neyagawa, Osaka572-8530, JAPAN
Hiroyuki Enomoto
Affiliation:
Osaka Electro-Communication University, Neyagawa, Osaka572-8530, JAPAN
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Abstract

We have prepared (Ca1−x−yMxBiy)3Co4Oz (M = Mg, Sr, and Ba) thin films by a combinatorial approach using a solution process. In the systems of (Ca1−x−yMxBiy)3Co4Oz (M = Mg, Sr, and Ba), solid solution range was determined to be × < 0.8 (M = Sr, y = 0), x < 1.0 (M = Mg, y = 0), x = 0.0 (M = Ba, y = 0), and x < 0.4 (M = Bi, x = 0). No solid solution range was obtained for the substitution of Ba for Ca site. The in-plane compressive stress in the CoO2 sublattice is controllable by the cation substitution for Ca in the (Ca2CoO3) sublattice. With increasing in-plane stress, the magnitude of thermoelectric power and resistivity increased.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 691: Symposium G – Thermoelectric Materials 2001--Research and Applications , 2001 , G12.2
Copyright
Copyright © Materials Research Society 2002

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References

REFERENCES

1. Terasaki, I., Sasago, Y., and Uchinokura, K., Phys. Rev. B56, 12685 (1997).Google Scholar
2. Yakabe, H., Kikuchi, K., Terasaki, I., Sasago, Y., and Uchinokura, K., Proc. 16th Int. Conf. on Thermoelectrics, 523 (1997).Google Scholar
3. Li, S., Funahashi, R., Matsubara, I., Ueno, K., and Yamada, H., J. Mater. Chem. 9, 1659 (1999).Google Scholar
4. Li, S., Funahashi, R., Matsubara, I., Ueno, K., and Yamada, H., Chem. Mater. 12, 2424 (2000).Google Scholar
5. Funahashi, R., Matsubara, I., Sodeoka, S., Ikuta, H., Takeuchi, T., and Mizutani, U., Jpn. J. Appl. Phys. 39, L1127 (2000).Google Scholar
6. Miyazaki, Y., Kudo, K., Akoshima, M., Ono, Y., Koike, Y., and Kajitani, T., Jpn. J. Appl. Phys. 39, L531 (2000).Google Scholar
7. Masset, A., Michel, C., Maignan, A., Hervieu, M., Toulemonde, O., Studer, F., and Raveau, B., Phys. Rev. B 62, 166 (2000).Google Scholar
8. Moon, J. W., Nagahama, D., Masuda, Y., Seo, W. S., and Koumoto, K., J. Ceram. Soc. Jpn, 109, 647 (2001)Google Scholar
9. Jandeleit, B., Schaefer, D. J., Powers, T. S., Turner, H. W., and Weinberg, W. H., Angew. Chem. Int. Ed., 38, 2495 (1999).Google Scholar
10. Lambert, S., Leligny, H., and Grebille, D., J. Solid State Chem. 160, 322 (2001).Google Scholar
11. Huber, H. and Wagener, S., Z. Tech. Physik 23, 1 (1942).Google Scholar
12. Greenwald, S., Acta Cryst. 6, 396 (1953).Google Scholar
13. Fujita, K., Mochida, T., Nakamura, K., Jpn. J. Appl. Phys. 40, 4644 (2001).Google Scholar
14. Funahashi, R., Matsubara, I., Ikuta, H., Takeuchi, T., and Mizutani, U., Mater. Trans. 42, 956 (2001).Google Scholar
15. Mandal, J. B., Das, A. N., and Ghosh, B., J. Phys. Condens. Matter. 8, 3047 (1996).Google Scholar