Hostname: page-component-cd9895bd7-gxg78 Total loading time: 0 Render date: 2025-01-01T14:11:55.307Z Has data issue: false hasContentIssue false
  • English
  • Français

Electrophoretic deposition of TiO2 nanopillars from stable colloidal solution.

Published online by Cambridge University Press:  20 June 2013

Vincent Jouenne ,
Jean-Luc Duvail ,
Luc Brohan  and
Mireille Richard-Plouet
Vincent Jouenne
Affiliation:
Institut des Matériaux Jean Rouxel (IMN), Université de Nantes, CNRS, 2 rue de la Houssinière BP 32229 44322 Nantes cedex 3 France
Jean-Luc Duvail
Affiliation:
Institut des Matériaux Jean Rouxel (IMN), Université de Nantes, CNRS, 2 rue de la Houssinière BP 32229 44322 Nantes cedex 3 France
Luc Brohan
Affiliation:
Institut des Matériaux Jean Rouxel (IMN), Université de Nantes, CNRS, 2 rue de la Houssinière BP 32229 44322 Nantes cedex 3 France
Mireille Richard-Plouet
Affiliation:
Institut des Matériaux Jean Rouxel (IMN), Université de Nantes, CNRS, 2 rue de la Houssinière BP 32229 44322 Nantes cedex 3 France
Get access

Abstract

Titanium dioxide nanoparticles were synthesized by solvothermal treatment in the presence of oleic acid and oleylamine. As Ti(IV) reactant, crystals of [Ti8O12 (H2O)24]Cl8, HCl, 7H2O were preferred because their hydrolysis and condensation can be controlled in ethanol/water solution. The organic surfactants allowed the control of the shape and they can be removed by an acid treatment of the particles. The TiO2 nanoparticles can then be re-dispersed in an ethanol-based charging solution. A fixed applied voltage promotes the electrophoretic deposition of the nanoparticles (<15 nm in size) into pores of anodized aluminium oxide (AAO) template.

Keywords

colloidelectrodepositionnanostructure
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1578: Symposium YY – Titanium Dioxide—Fundamentals and Applications , 2013 , mrss13-1578-yy01-08
Copyright
Copyright © Materials Research Society 2013 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Sarkar, P. and Nicholson, P. S., J. Amer. Ceram. Soc. 79, 1987 (1996).CrossRefGoogle Scholar
Besra, L. and Liu, M., Progress in Materials Science 52, 1–61 (2007).CrossRefGoogle Scholar
Chávez-Valdez, A. and Boccaccini, A. R., Electrochim. Acta 65, 70–89 (2012).CrossRefGoogle Scholar
Corni, I., Ryan, M. P. and Boccaccini, A. R., J Europ. Ceram. Soc. 28, 1353–1367 (2008).CrossRefGoogle Scholar
Chang, H., Su, H.-T., Chen, W.-A., David Huang, K., Chien, S.-H., Chen, S.-L. and Chen, C.-C., Solar Energy 84, 130–136 (2010).CrossRefGoogle Scholar
Chen, L.-C., Ting, J.-M., Lee, Y.-L. and Hon, M.-H., J. Mater. Chem. 22, 5596–5601 (2012).CrossRefGoogle Scholar
Grinis, L., Dor, S., Ofir, A. and Zaban, A., J. Photochem. Photobiol. A 198, 52–59 (2008).CrossRefGoogle Scholar
Liou, Y.-J., Hsiao, P.-T., Chen, L.-C., Chu, Y.-Y. and Teng, H., J. Phys. Chem. C 115, 25580–25589 (2011).CrossRefGoogle Scholar
Grimes, C.A., Varghese, O.K. and Ranjan, S., Light, Water, Hydrogen, Springer Berlin, 2008.CrossRefGoogle Scholar
Bhushan, B., Springer Handbook of Nanotechnology, 3rd ed. Springer: Berlin, 2010 CrossRefGoogle Scholar
Cao, G. Z., Liu, D. W., Adv. Coll. Interf. Sci. 136, 45–64 (2008).CrossRefGoogle Scholar
Fori, B., Taberna, P.-L., Arurault, L., Bonino, J.-P., Gazeau, C., Bares, P., Coll. Surf. A 415 187 (2012).CrossRefGoogle Scholar
Buonsanti, R., Carlino, E., Giannini, C., Altamura, D., De Marco, L., Giannuzzi, R., Manca, M., Gigli, G., Cozzoli, P. D., J. Amer. Chem. Soc. 133(47), 19216–19239 (2011).CrossRefGoogle Scholar
Liu, C. E., Rouet, A., Sutrisno, H., Puzenat, E., Terrisse, H., Brohan, L. and Richard-Plouet, M., Chem. Mater. 20, 4739–4748 (2008).CrossRefGoogle Scholar
Karpinski, A., Berson, S., Terrisse, H., Mancini-Le Granvalet, M., Guillerez, S., Brohan, L., Richard-Plouet, M., Solar En. Mater & SolarCells 116, 27–33 (2013).L. Brohan, A. Karpinski, M. Richard-Plouet, S. Berson, S. Guillerez, M. Barret, French CNRS-CEA, ARDEJE, Patent N°11 58275, Sept 16, 2011, PCT/EP2012/067829, Sept 12, 2012.CrossRefGoogle Scholar
Brohan, L., Sutrisno, H., Puzenat, E., Rouet, A., Terrisse, H., French CNRS Patent FR2854623, issued July 7, 2006 International Publication WO 2004/101436 A2, Nov 25, 2004 European CNRS patent EP 04 742 604.4, Nov 24, 2005 Japan CNRS Patent JP 4697808 issued Jan 25, 2011 United States CNRS Patent US 7858064 issued Dec 28, 2011.Google Scholar
Dor, S., Rühle, S., Ofir, A., Adler, M., Grinis, L., Zaban, A., Coll. and Surf. A 342, 70 (2009).CrossRefGoogle Scholar
Duvail, J.L., Retho, P., Fernandez, V., Louarn, G., Molinie, P., Chauvet, O., J. Phys. Chem. B 108, 18552 (2004).CrossRefGoogle Scholar
Li Bassi, A., Cattaneo, D., Russo, V., and Bottani, C. E., J. Appl. Phys. 98, 074305 (2005).CrossRefGoogle Scholar