Hostname: page-component-78c5997874-v9fdk Total loading time: 0 Render date: 2024-11-14T07:52:08.452Z Has data issue: false hasContentIssue false
  • English
  • Français

Hierarchical 3D Nanocomposites towards Advanced Electrochemical Energy Storage

Published online by Cambridge University Press:  28 March 2013

Jiahua Zhu ,
Suying Wei  and
Zhanhu Guo
Jiahua Zhu
Affiliation:
Integrated Composites Laboratory (ICL), Dan F. Smith Department of Chemical Engineering, Lamar University, Beaumont, TX, 77710USA
Suying Wei
Affiliation:
Department of Chemistry and Biochemistry, Lamar University, Beaumont, TX 77710, USA
Zhanhu Guo*
Affiliation:
Integrated Composites Laboratory (ICL), Dan F. Smith Department of Chemical Engineering, Lamar University, Beaumont, TX, 77710USA
*
*zhanhu.guo@lamar.edu
Get access

Abstract

Polyaniline nanofibers (PANI-NFs)/graphite oxide (GO) nanocomposites with excellent interfacial interaction and elongated fiber structures were synthesized via a facile interfacial polymerization method. This method efficiently exfoliated the expanded layer structure of GO into individual sheet and thus significantly enhanced the specific surface area. The reduced diameter of PANI-NFs in PANI-NF/GO than that of pure PANI-NFs could shorten the diffusion distance and enhance the electro-active sites. The PANI-NFs/GO hybrid materials showed orders of magnitude enhancement in capacitance and better cycling stability than that of individual GO and PANI-NF components.

Keywords

energy storagenanostructurepolymer
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1497: Symposium K – Hierarchically Structured Materials for Energy Conversion and Storage , 2013 , mrsf12-1497-k06-12
Copyright
Copyright © Materials Research Society 2013

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Zhang, W. L., Park, B. J. and Choi, H. J., Chem. Commun. 46, 5596–5598 (2010).CrossRefGoogle Scholar
Wang, D.-W., Li, F., Zhao, J., Ren, W., Chen, Z.-G., Tan, J., Wu, Z.-S., Gentle, I., Lu, G. Q. and Cheng, H.-M., ACS Nano 3, 1745–1752 (2009).CrossRefGoogle Scholar
Xu, J., Wang, K., Zu, S.-Z., Han, B.-H. and Wei, Z., ACS Nano 4, 5019–5026 (2010).CrossRefGoogle Scholar
Zhang, K., Zhang, L. L., Zhao, X. S. and Wu, J., Chem. Mater 22, 1392–1401(2010).CrossRefGoogle Scholar
Wu, Q., Xu, Y., Yao, Z., Liu, A. and Shi, G., ACS Nano 4, 1963–1970 (2010).CrossRefGoogle Scholar
Hummers, W. S. and Offeman, R. E., J. Am. Chem. Soc. 80, 1339–1339 (1958).CrossRefGoogle Scholar
Kovtyukhova, N. I., Ollivier, P. J., Martin, B. R., Mallouk, T. E., Chizhik, S. A., Buzaneva, E. V. and Gorchinskiy, A. D., Chem. Mater. 11, 771–778 (1999).CrossRefGoogle Scholar
Li, X., Zhang, G., Bai, X., Sun, X., Wang, X., Wang, E. and Dai, H., Nat. Nanotechnol. 3, 538–542 (2008).CrossRefGoogle Scholar
Murugan, A. V., Muraliganth, T. and Manthiram, A., Chem. Mater. 21, 5004–5006 (2009).CrossRefGoogle Scholar
Lotya, M., Hernandez, Y., King, P. J., Smith, R. J., Nicolosi, V., Karlsson, L. S., Blighe, F. M., De, S., Wang, Z., McGovern, I. T., Duesberg, G. S. and Coleman, J. N., J. Am. Chem. Soc. 131, 3611–3620 (2009).CrossRefGoogle Scholar
Ferrari, A. C., Solid State Commun. 143, 47–57 (2007).CrossRefGoogle Scholar
Lu, J., Yang, J.-x., Wang, J., Lim, A., Wang, S. and Loh, K. P., ACS Nano 3, 2367–2375 (2009).CrossRefGoogle Scholar
Lapkowski, M., Berrada, K., Quillard, S., Louarn, G., Lefrant, S. and Pron, A., Macromolecules 28, 1233–1238 (1995).CrossRefGoogle Scholar
Ohira, M., Sakai, T., Takeuchi, M., Kobayashi, Y. and Tsuji, M., Synth. Met. 18, 347–352 (1987).CrossRefGoogle Scholar
Wang, G., Yang, J., Park, J., Gou, X., Wang, B., Liu, H. and Yao, J., J Phys Chem C 112, 8192–8195 (2008).CrossRefGoogle Scholar
McAllister, M. J., Li, J.-L., Adamson, D. H., Schniepp, H. C., Abdala, A. A., Liu, J., Herrera-Alonso, M., Milius, D. L., Car, R., Prud'homme, R. K. and Aksay, I. A., Chem. Mater. 19, 4396–4404 (2007).CrossRefGoogle Scholar
Zhang, X., Zhu, J., Haldolaarachchige, N., Ryu, J., Young, D. P., Wei, S. and Guo, Z., Polymer 53(10), 2109–2120 (2012).CrossRefGoogle Scholar
Zhu, J., Wei, S., Zhang, L., Mao, Y., Ryu, J., Haldolaarachchige, N., Young, D. P. and Guo, Z., J. Mater. Chem. 21, 3952–3959 (2011).CrossRefGoogle Scholar
Zhu, J., Chen, M., Qu, H., Luo, Z., Wu, S., Colorado, H. A., Wei, S. and Guo, Z., Energy Environ. Sci. DOI: 10.1039/C2EE23422J (2012).Google Scholar
Wang, G., Zhang, L. and Zhang, J., Chem. Soc. Rev. 41, 797–828 (2012).CrossRefGoogle Scholar
Zhu, J., Chen, M., Qu, H., Zhang, X., Wei, H., Luo, Z., Colorado, H. A., Wei, S. and Guo, Z., Polymer. DOI: 10.1016/j.polymer.2012.10.002 (2012)Google ScholarPubMed