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The Hydrothermal Synthesis of Layered Molybdenum Phosphates with Octahedral-Tetrahedral Layers

Published online by Cambridge University Press:  15 February 2011

Robert C. Haushalter  and
Linda A. Mundi
Robert C. Haushalter
Affiliation:
Exxon Research and Engineering Co., Rt. 22E, Annandale, NJ, 08801
Linda A. Mundi
Affiliation:
Exxon Research and Engineering Co., Rt. 22E, Annandale, NJ, 08801
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Abstract

While we have prepared and structurally characterized over forty solids in the octahedral-tetrahedral framework molybdenum phosphate (MoPO) system, including molecules, 1-D polymers and 3-D materials, this paper will focus on the two dimensional layered MoPO's. Both covalently and H bonded layers will be discussed. Compounds covered include Na3[Mo2O4(HPO4)(PO4)]·2H2O, (Et2NH2)2[Mo4O8(PO4)4/2], Cs2Mo4P6O26, (4-phenylpyridie)2[Mo4O8(PO4)4/2], (cation)[Mo2O2(PO4)2(H2PO4)], with several different types of organic and inorganic cations, and (4-phenylpiperidine)4[Na2.5Mo6O15(H1.4PO4)4]·4H2O. These materials might provide a platform for the preparation of new types of pillared and intercalated inorganic solids.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 233: Symposium U – Synthesis/Characterization and Novel Applications of Molecular Sieve Materials , 1991 , 255
Copyright
Copyright © Materials Research Society 1991

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References

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