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Irradiation-Enhanced Second-Phase Precipitation in Zr-Fe Nanocrystalline Thin Films

Published online by Cambridge University Press:  26 February 2011

Djamel Kaoumi ,
Arthur T. Motta  and
Robert C. Birtcher
Djamel Kaoumi
Affiliation:
dxk909@psu.edu, Pennsylvania State University, Mechanical and Nuclear Engineering, 18 Reber Bldg, University Park, PA, 16802, United States, 8148832611
Arthur T. Motta
Affiliation:
atm2@psu.edu, Pennsylvania State University, Mechanical and Nuclear Engineering, United States
Robert C. Birtcher
Affiliation:
birtcher@anl.gov, Argonne National Laboratory, Materials Science Division, United States
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Abstract

In situ observations in a transmission electron microscope (TEM) were used to study ion-beam enhancement of second-phase precipitation in Zr-Fe nanocrystalline thin films. The free-standing films were prepared by co-sputter deposition with an Fe content of 1.2 at%. TEM diffraction analysis showed that only the hcp Zr crystal structure was present in the as-deposited films. No second phases were detected, although Rutherford Backscattering Spectroscopy (RBS) confirmed a Fe content beyond the solubility limit of Fe in Zr (of the order of ppm). This means the thin films were Zr solid solutions supersaturated with Fe. Heat treatment in the absence of irradiation was observed to cause precipitation of the Zr2Fe intermetallic phase, but only above 673 K. The same second-phase precipitation can occur at lower temperatures in the presence of ion irradiation. Samples were irradiated in-situ at the Intermediate Voltage Electron Microscope (IVEM) at Argonne National Laboratory with Kr ions to fluences in excess of 1016 ion/cm2, at temperatures ranging from 50 to 573 K. Second phase precipitation was detected by electron diffraction patterns and by dark field imaging comparing regions exposed to the beam with regions protected from the beam by the TEM support grid. Precipitation of Zr2Fe intermetallic phase was observed at all irradiating temperatures above room temperature. In the bulk, this phase is thermodynamically metastable in the range of temperatures investigated (relative to the orthorhombic Zr3Fe intermetallic phase). The kinetics of the irradiation-enhanced second-phase precipitation was followed by recording the diffraction patterns at regular intervals. The dose to precipitation was found to decrease with increasing irradiation temperature.

Keywords

ion-solid interactionssecond phasestransmission electron microscopy (TEM)
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 908: Symposium OO – Growth, Modification, and Analysis by Ion Beams at the Nanoscale , 2005 , 0908-OO04-04
Copyright
Copyright © Materials Research Society 2006

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