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Published online by Cambridge University Press: 01 February 2011
It is generally accepted that the hardness of silicon and germanium is limited by a phase transformation. Observations of the deformation under indents using transmission electron microscopy indicate that, in addition to the phase transformation, there is also plastic flow both in the transformed and in the untransformed material. These observations are consistent with those made elsewhere and with predictions based on the spherical cavity model for indentation, modified to quantify the effect of a phase transformation on the measured hardness. The analysis predicts that the hardness can only be approximately equal to the transformation pressure provided the yield strength of the transformed material is low, and that there is a region where plastic deformation in the untransformed material can occur in addition to the phase transformation. These predictions are consistent with the experimental observations of substantial plastic deformation of the transformed phase, as well as with estimates of its Peierls stress.