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Multi-Phasic Nanocomposite Sol-Gel Processing of Cordierite

Published online by Cambridge University Press:  25 February 2011

Ann Kazakos-Kijowski
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802
Sridhar Komarneni
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802
Rustum Roy
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802
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Abstract

Cordierite (Mg2Al4Si5O18) powders prepared from compositionally triphasic nanocomposite gels led to enhanced densification when compared to powders made by the conventional SSG route. The densification of the sintered cordierite pellets was determined by utilizing the Archimedes method and the microstructure of the pellets was examined with a scanning electron microscope (SEM). Bulk densities of monophasic, triphasic nanocomposite (two sols and one solution) and truly triphasic nanocomposite (three sols) pellets sintered at 1300°C for 2 hours were 2.01 g/cm 3 (80% relative density), 2.42 g/cm 3 (96% relative density) and 2.51 g/cm 3 (100% relative density) respectively. The enhanced densification of α-cordierite utilizing triphasic nanocomposite sol-gel processing is, at least in part, due to the contribution of the heat of reaction from the three components.

Type
Research Article
Copyright
Copyright © Materials Research Society 1988

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References

REFERENCES

Roy, R. and Osborn, E. F., Am. Mineral. 39, (11/12) 853 (1954).Google Scholar
2. Hill, V. G., Roy, R., and Osborn, E. F., J. Am. Ceram. Soc. 35, (6) 115 (1952).Google Scholar
3. Roy, D. M. and Roy, R., Am. Mineral. 39, (11/12) 957 (1954).Google Scholar
4. Roy, R., J. Am. Ceram. Soc. 39, (4) 145 (1956).CrossRefGoogle Scholar
5. Ewell, R. H. and Insley, H., J. Natl. Bur. Stand. 15, (2) 173 (1935).CrossRefGoogle Scholar
6. Roy, R. A. and Roy, R., Abstracts, Annual Meeting of Materials Research Society, (Boston, MA 1982) p. 377.Google Scholar
7. Roy, R. A. and Roy, R., Mat. Res. Bull. 19, (2) 169 (1984).Google Scholar
8. Hoffman, D. W., Roy, R. and Komarneni, S., J. Am. Ceram. Soc. 67, (7) 468 (1984).Google Scholar
9. Roy, R., Komarneni, S., and Roy, D. M. in Better Ceramics Through Chemistry, edited by Brinker, C. J. et al. (Elsevier Science Publishers, New York, 1984), p.441.Google Scholar
10. Hoffman, D. W., Roy, R. and Komarneni, S., Mat. Lett. 2, (3) 245 (1984).Google Scholar
11. Hoffman, D. W., Komarneni, S. and Roy, R., J. Mat. Sci. Lett. 3, (6) 439 (1984).Google Scholar
12. Komarneni, S., Suwa, Y. and Roy, R., J. Am. Ceram. Soc. 69, (7) C155 (1986).Google Scholar
13. Suwa, Y., Roy, R. and Komarneni, S., J. Am. Ceram. Soc. 68, (9) C238 (1985).Google Scholar
14. Roy, R., Suwa, Y., and Komarneni, S., in Science of Ceramic Chemical Processing, edited by Hench, L. L. and Ulrich, D. R., (Wiley Publishers, New York, 1986), p. 247.Google Scholar
15. Suwa, Y., Komarneni, S. and Roy, R., J. Mat. Sci. Lett. 5, (1) 21 (1986).CrossRefGoogle Scholar
16. Suwa, Y., Roy, R. and Komarneni, S., Mat. Sci. Eng. 83, 151 (1986).CrossRefGoogle Scholar
17. Kumagi, M. and Messing, G. L., J. Am. Ceram. Sci. 67, (11) C230 (1984).Google Scholar
18. Kumagi, M. and Messing, G. L., J. Am. Ceram. Sci. 68, (9) 500 (1985).Google Scholar
19. Vilmin, G., Komarneni, S. and Roy, R., J. Mat. Sci. 22, 3556 (1987).Google Scholar
20. Vilmin, G., Komarneni, S. and Roy, R., J. Mat. Res. 2, 489 (1987).CrossRefGoogle Scholar
21. Komarneni, S., Suwa, Y., and Roy, R., J. Mat. Sci. Lett. 6, 525 (1987).Google Scholar
22. Bernier, J. C., Rehspringer, J. L., Vilminot, S. and Poix, P. in Better Ceramics Through Chemistry II, edited by Brinker, C. J. et al. (Elsevier Science Publishers, New York, 1986), p. 129.Google Scholar
23. Moyer, J. R., Prunier, A.R. Jr, Hughes, N. N., and Wintcrton, R. C. in Better Ceramics Through Chemistry II. edited by Brinker, C. J. et al. (Elscvicr Science Publishers, New York, 1986), p. 117.Google Scholar