Hostname: page-component-78c5997874-dh8gc Total loading time: 0 Render date: 2024-11-10T11:43:12.986Z Has data issue: false hasContentIssue false
  • English
  • Français

Nanocomposites by Covalent Bonding between Inorganic Nanoparticles and Polymers

Published online by Cambridge University Press:  21 March 2011

Yigal D. Blum ,
Nobuyuki Kambe ,
D. Brent MacQueen ,
Sujeet Kumar ,
Shiv Chiruvolu  and
Benjamin Chaloner-Gill
Yigal D. Blum
Affiliation:
Chemical Science and Technology Laboratory, SRI International 333 Ravenswood Ave, Menlo Park, CA 94025, U. S. A.
Nobuyuki Kambe
Affiliation:
NanoGram Corporation 46774 Lakeview Blvd., Fremont, CA 94538, U. S. A.
D. Brent MacQueen
Affiliation:
Chemical Science and Technology Laboratory, SRI International 333 Ravenswood Ave, Menlo Park, CA 94025, U. S. A.
Sujeet Kumar
Affiliation:
NanoGram Corporation 46774 Lakeview Blvd., Fremont, CA 94538, U. S. A.
Shiv Chiruvolu
Affiliation:
NanoGram Corporation 46774 Lakeview Blvd., Fremont, CA 94538, U. S. A.
Benjamin Chaloner-Gill
Affiliation:
NanoGram Corporation 46774 Lakeview Blvd., Fremont, CA 94538, U. S. A.
Get access

Abstract

A generic approach to chemically facilitate the interactions of nanoparticles with conventional polymers is developed to address the design and processing capability of inorganic-organic nanocomposites. This approach introduces homogeneity to the composite and can be used as a tailoring tool for microstructure architecture.

Nanoparticles produced by NanoGram's technology are excellent for such nanocomposites. Their spherical shape and narrow size distribution assist in the processing of homogeneous blends. High loads of particles within a polymeric matrix can be achieved without losing homogeneity. Alternatively, the particles can be selectively attracted into desired domains.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 676: Symposium Y – Synthesis, Functional Properties and Applications of Nanostructures , 2001 , Y1.8
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] (a) Shipway, A. N., Katz, E. and Willner, I, ChemPhysChem, 1, 18 (2000);Google Scholar
(b) Mirkin, C. A., Letsinger, R. L., Mucic, R. C. and Storhof, J. J., Nature 382, 607 (1996).Google Scholar
(c) Baney, R. H., Itoh, M., Sakakibara, A. and Suzuki, T., Chem. Rev. 1409 (1995);Google Scholar
(d) Gilman, J. W., Schlitzer, D. S., and Lichtenhan, J. D., J. Appl. Pol. Sci., 60, 591 (1996);Google Scholar
(e) Blum, Y. D., Chen, H. P., MacQueen, D. B., and Johnson, S. M., in Organic/Inorganic Hybrid Materials II, MRS Proceedings, Vol. 576, 281 (1999).Google Scholar
[2] (a) Schmidt, H. K., Oliveira, P. W., and Krug, H., in Mat. Res. Soc. Symp. Proc. 435, 13–24 (1996);Google Scholar
(b) Schmidt, H., in Ultrastructure Processing of Advanced Materials, John Wiley & Sons, Inc. (1992), pp. 409–423.Google Scholar
[3] (a) Baney, R. H. and Chi, F. K., US Patent 4,275,118 (1979);Google Scholar
Shiratsuchi, K. and Hokazono, H., US Patent 5,856,379 (1997);Google Scholar
(b) Morrison, Eric D., U. S. Patent Number 5,407,603 (1995);Google Scholar
(c) Lal, M., Joshi, M., Kumar, D. N., Friend, C. S., Winiarz, J., Asefa, T., Kim, K., and Prasad, P. N., in Mat. Res. Soc. Symp. Proc. Vol. 519 (1998), p 217.Google Scholar
Boal, A., Ilhan, F., DeRouchey, J., Thurn-Albrecht, T., Russwll, T., Rotello, V., Nature, 2000, 404, 746–749.Google Scholar
[4] (a) Usuki, A., Kojima, Y., Kawasumi, M., Okada, A., Fukushima, Y., Kurauchi, T. and Kamigaito, O., J. Mater. Res. 8, 1179 (1993);Google Scholar
(b) Mesersmith, P. B. and Giannelis, E. P., J. Polym. Sci. Part A: Polym. Chem. 33, 1047 (1995).Google Scholar
[5] Kambe, N., Kumar, S., Chiruvolu, S., Chaloner-Gill, B., Blum, Y. D., MacQueen, D. B. and Faris, G. W., Materials Research Society, Spring Meeting Abstracts, Symposium Y (2001); submitted for publication in Vol. 676 in MRS Proceedings Series.Google Scholar
[6] (a) Bates, F. S. and Fredrickson, G. H., Physics Today, 32 (February 1999);Google Scholar
(b) Ho, K. M., Chan, C. T., Soukoulis, C.M., Biswas, R. and Sigalas, M., Solid State Communications, 89, 413, (1994);Google Scholar
(c) Lehn, J. M., Supramulecular Chemistry, VCH, Weinheim and New York (1995)Google Scholar
[7] Bi, X. and Kambe, N., US Patent 5,958,348 (1999).Google Scholar