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Published online by Cambridge University Press: 15 March 2011
P olarizedresonant Raman spectra for the G-band were obtained from a rope of aligned semiconducting SWNTs and from nonaligned semiconducting and metallic SWNTs. Based on group theory analysis and related theoretical predictions, we assign the symmetry for the modes in the G-band of both metallic and semiconducting SWNTs. he frequency shifts of the tangential G modes from the 2D graphite-like E2g2 frequency are discussed in terms of the nanotube geometry.