Hostname: page-component-78c5997874-ndw9j Total loading time: 0 Render date: 2024-11-14T09:20:29.671Z Has data issue: false hasContentIssue false
  • English
  • Français

Raman Spectroscopy for Probing guest-host interactions in Metal Organic Frameworks

Published online by Cambridge University Press:  22 August 2011

Nour Nijem ,
Katy Roodenko ,
Yonggang Zhao ,
Jing Li  and
Yves J. Chabal
Nour Nijem
Affiliation:
Department of Materials Science and Engineering, University of Texas at Dallas, Richardson, Texas 75080, U.S.A.
Katy Roodenko
Affiliation:
Department of Materials Science and Engineering, University of Texas at Dallas, Richardson, Texas 75080, U.S.A.
Yonggang Zhao
Affiliation:
Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, New Jersey 08854, U.S.A.
Jing Li
Affiliation:
Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, New Jersey 08854, U.S.A.
Yves J. Chabal
Affiliation:
Department of Materials Science and Engineering, University of Texas at Dallas, Richardson, Texas 75080, U.S.A.
Get access

Abstract

Spectroscopic techniques such as IR and Raman are very powerful to understand guest-host interactions. Although these techniques are complementary, Raman spectroscopy has not been widely implemented as a tool to characterize these interactions. This study illustrates the use of Raman spectroscopy not only to probe the interactions experienced by a guest molecule but also to detect structural changes occurring in the framework upon loading. Weak interactions of adsorbed molecules with the framework are reflected in frequency and intensity variations in both Raman and IR absorption lines, as shown for the case of CO2, N2 and CH4 with Zn(bdc)(ted)0.5.

Keywords

Raman spectroscopymethaneIr
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1334: Symposium N – Recent Developments in Materials for Hydrogen Storage and Carbon-Capture Technologies , 2011 , mrss11-1334-n06-06
Copyright
Copyright © Materials Research Society 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

(1) Centrone, A.; Siberio-Pérez, D. Y.; Millward, A. R.; Yaghi, O. M.; Matzger, A. J.; Zerbi, G. Chemical Physics Letters 2005, 411, 516–519.10.1016/j.cplett.2005.06.069Google Scholar
(2) Nakamoto, K. Infrared and Raman Spectra of Inorganic and coordination compounds; Fifth ed.; John Wiley and Sons Inc.; Vol. B.Google Scholar
(3) Siberio-Perez, D. Y.; Wong-Foy, A. G.; Yaghi, O. M.; Matzger, A. J. Chemistry of Materials 2007, 19, 3681–3685.10.1021/cm070542gGoogle Scholar
(4) Vimont, A.; Travert, A.; Bazin, P.; Lavalley, J.-C.; Daturi, M.; Serre, C.; Ferey, G.; Bourrelly, S.; Llewellyn, P. L. Chemical Communications 2007, 3291–3293.Google Scholar
(5) Kuppler, R. J.; Timmons, D. J.; Fang, Q.-R.; Li, J.-R.; Makal, T. A.; Young, M. D.; Yuan, D.; Zhao, D.; Zhuang, W.; Zhou, H.-C. Coordination Chemistry Reviews 2009, 253, 3042–3066.10.1016/j.ccr.2009.05.019Google Scholar
(6) Hamon, L.; et al. . Journal of the American Chemical Society 2009, 131, 17490–17499.10.1021/ja907556qGoogle Scholar
(7) Li, J.-R.; Kuppler, R. J.; Zhou, H.-C. Chemical Society Reviews 2009, 38, 1477–1504.Google Scholar
(8) Nijem, N.; Veyan, J.-F. o.; Kong, L.; Wu, H.; Zhao, Y.; Li, J.; Langreth, D. C.; Chabal, Y. J. Journal of the American Chemical Society 2010, 132, 14834–14848.10.1021/ja104923fGoogle Scholar
(9) Nijem, N.; Veyan, J.-F.; Kong, L.; Li, K.; Pramanik, S.; Zhao, Y.; Li, J.; Langreth, D.; Chabal, Y. J. Journal of the American Chemical Society 2010, 132, 1654–1664.Google Scholar
(10) Nijem, N.; Kong, L.; Zhao, Y.; Wu, H.; Li, J.; Langreth, D. C.; Chabal, Y. J. Journal of the American Chemical Society 2011, 133, 4782–4784.10.1021/ja2010863Google Scholar
(11) Lee, J. Y.; Olson, D. H.; Pan, L.; Emge, T. J.; Li, J. Advanced Functional Materials 2007, 17, 1255–1262.10.1002/adfm.200600944Google Scholar
(12) Zhao, Y.; Wu, H.; Emge, T. J.; Gong, Q.; Nijem, N.; Chabal, Y. J.; Kong, L.; Langreth, D. C.; Liu, H.; Zeng, H.; Li, J. Chemistry – A European Journal, 17, 5101–5109.10.1002/chem.201002818Google Scholar
(13) Fenner, W. R.; Hyatt, H. A.; Kellam, J. M.; Porto, S. P. S. J. Opt. Soc. Am. 1973, 63, 73–77.Google Scholar
(14) Dietzel, P. D. C.; Johnsen, R. E.; Fjellvag, H.; Bordiga, S.; Groppo, E.; Chavan, S.; Blom, R. Chemical Communications 2008, 5125–5127.10.1039/b810574jGoogle Scholar