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Static Dissolution of α-doped UO2 in Boom Clay Conditions: Preliminary Results

Published online by Cambridge University Press:  01 February 2011

C. Cachoir  and
K. Lemmens
C. Cachoir
Affiliation:
Waste and Disposal Department, SCK•CEN, Boeretang 200, B-2400 Mol, Belgium.
K. Lemmens
Affiliation:
Waste and Disposal Department, SCK•CEN, Boeretang 200, B-2400 Mol, Belgium.
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Abstract

To support the performance assessment (PA) calculations for the possible final disposal of spent fuel in the Boom Clay, leach experiments are performed with α-doped UO2 in clay media, simulating various near field ages. The experiments allow to measure the dissolution rate of the UO2 and to determine the assumed relationship between dissolution rate and α-activity. Tests are performed at six different α-activities, simulating various fuel ages, at 25–30°C, for durations ranging from 90 to 720 days, in a glove box with Ar/0.4%CO2 atmosphere. The solutions and solids are analyzed for U isotopes and 238Pu by radiochemical measurement and by ICP-MS. The dissolution rates of the α-doped UO2 are presented for different durations. The resulting corrosion rate is around 300 μgU.m−2.d−1. This is up to 100 times higher than found for similar conditions in the literature. In the presence of clay, there appears to be no correlation between the α-activity and the corrosion rate of the α-doped UO2.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 807: Symposium Scientific Basis for Nuclear Waste Management XXVII , 2003 , 59
Copyright
Copyright © Materials Research Society 2004

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