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Published online by Cambridge University Press: 01 February 2011
The results of calorimetric and electrical studies of bulk Ge2Sb2Te5 and GeSb2Te4 alloys around melting temperature Tm are presented together with characteristics of phase-change memory devices from such alloys. The endothermic melting region is wider in Ge2Sb2Te5 than GeSb2Te4. Electrical resistivities of the alloys in this region have semiconductor characteristics. The width of the melting region correlates with breadth of set to reset transition in devices. This empirical correlation is probably important for alloy selection for multi-level memory cells.