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Synthesis and Characterization of Rare Earth (Tb3+ and Yb3+) Doped CdS/ZnS Core/Shell Nanocrystals for Enhanced Photovoltaic Efficiency

Published online by Cambridge University Press:  18 August 2011

Sandip Das  and
Krishna C. Mandal
Sandip Das
Affiliation:
Department of Electrical Engineering, University of South Carolina, Columbia, SC 29208, USA
Krishna C. Mandal
Affiliation:
Department of Electrical Engineering, University of South Carolina, Columbia, SC 29208, USA
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Abstract

CdS host nanocrystals with 4.2-5.5 nm in diameter have been synthesized from air stable precursors via a synthetic chemical route and doped with rare earth (RE) terbium (Tb3+) and ytterbium (Yb3+) ions. RE3+-doped CdS cores were shelled by ZnS layers of different thicknesses. The resulting core/shell nanocrystals show a complete broadband absorption below 400-460 nm to the deep UV region depending on the size of the cores. RE3+-doped CdS nanocrystals showed a red shift in the emission as observed under irradiation of 302 nm UV light and was confirmed by room temperature photoluminescence (PL) measurements. The nanocrystals were further characterized by x-ray diffraction (XRD), transmission electron microscopy (TEM), and energy dispersive x-ray (EDX) analysis. The results show that these RE3+-doped nanocrystals can be used as solar spectral matching downconversion material to enhance photovoltaic efficiency of existing solar cells.

Keywords

photovoltaiccore/shelloptical properties
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1322: Symposium B – Third-Generation and Emerging Solar-Cell Technologies , 2011 , mrss11-1322-b05-42
Copyright
Copyright © Materials Research Society 2011

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