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Thermal Properties of Boron-Rich Borides

Published online by Cambridge University Press:  25 February 2011

H. E. Fischer
Affiliation:
ONR graduate fellow
E. T. Swartz
Affiliation:
Laboratory of Atomic and Solid State Physics
P. R. H. Türkes
Affiliation:
Laboratory of Atomic and Solid State Physics
R. O. Pohl
Affiliation:
Laboratory of Atomic and Solid State Physics
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Abstract

The specific heats of β-B and of B4C have been reviewed, and measurements of a different sample of B4C have been carried out below 80 K. A specific heat anomaly observed previously in boron carbides has been shown to be extrinsic in origin. The thermal conductivity of B1−x Cx, for x < 0.20, between 0.2 and 2000 K has also been reviewed, and recent measurements have been added. The magnitude and temperature dependence of the conductivity are somewhat similar to what is expected for amorphous boron, except for the characteristic plateau which is not clearly discernible. A possible explanation for the strong phonon scattering is discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1987

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References

REFERENCES

1. Türkes, P.R.H., Swartz, E.T., and Pohl, R.O., in Boron-Rich Solids, AIP Conference Proceedings 140, American Institute of Physics, New York, 1986, edited by Emin, D., Aselage, T., Beckel, C.C., Howard, I.A., and Wood, C..Google Scholar
2. Swartz, E.T., Rev. Scient. Instrum. 57, 2848 (1986).Google Scholar
3. Türkes, P.R.H., Ph.D. Thesis, Erlangen University, Fed. Rep. Germany, unpublished.Google Scholar
4. Cahill, D.G. and Pohl, R.O., Phys. Rev. B 35, 4067 (1987).Google Scholar
5. Cahill, D.G., Fischer, H.E., and Pohl, R.O., unpublished.Google Scholar
6. Johnston, H.L., Hersh, H.N., Kerr, E.C., J. Am. Chem. Soc. 73, 1112 (1951).Google Scholar
7. Kelley, K.K., J. Am. Chem. Soc. 63, 1137 (1941).Google Scholar
8. Wood, C., Zoltan, A., Emin, D., Gray, P., in Thermal Conductivity 18, Ashworth, T. and Smith, D.R., eds. Plenum 1985, p. 139.Google Scholar
9. Bouchacourt, M. and Thevenot, F., J. Mat. Sci. 20, 1237 (1985).Google Scholar
10. Moss, M., these Proceedings.Google Scholar
11. Talley, C.P., Line, L.E., and Overman, Q.D. in Boron: Synthesis, Structure, and Properties, Kohn, J. A. et at., eds. Plenum 1960, p. 94.Google Scholar
12. Golikova, O.A., Zaitsev, V.K., Orlov, V.M., Petrov, A.V., Stilbans, L.S., Tkalenko, E.N., Phys. Stat. Sol. (a) 21, 405 (1974).Google Scholar
13. Emin, D., Howard, I.A., Green, T.A., and Beckel, C.L., these Proceedings.Google Scholar
14. Kenkre, V. M. and Fan, X., these Proceedings.Google Scholar
15. Slack, G.A., Oliver, D.W., Horn, F.H., Phys. Rev. B 4, 1714 (1971).Google Scholar
16. Reviewed in Pohl, R.O., DeYoreo, J.J., Meissner, M., and Knaak, W., in Physics of Disordered Materials edited by Adler, D., Fritzsche, H., and Ovshinsky, S.R., Plenum (1985), p. 529.Google Scholar
17. Cahill, D.G., Cornell University, unpublished data.Google Scholar