Hostname: page-component-78c5997874-8bhkd Total loading time: 0 Render date: 2024-11-10T09:25:19.194Z Has data issue: false hasContentIssue false

An Evaluation on The Effects of Newly Designed Abrasives in CMP Slurry

Published online by Cambridge University Press:  18 March 2011

Nobuo Kawahashi
Affiliation:
Fine Electronic Research Laboratory, JSR Corporation 100 Kawajiri-cho, Yokkaichi, Mie, 510-8552, JAPAN
Masayuki Hattori
Affiliation:
Fine Electronic Research Laboratory, JSR Corporation 100 Kawajiri-cho, Yokkaichi, Mie, 510-8552, JAPAN
Get access

Abstract

Newly designed abrasives with various particle morphology and component have been prepared and evaluated in terms of polish efficiency for CMP application. Polymer sphere with uniformed particle size and special functional group were prepared by soap-free emulsion polymerization. CMP slurry including polymer abrasives indicated characteristic properties such as dishing, erosion and low defectivity for metal and dielectric surface. This study has been also conducted on the preparation of composite particles consisting of polymer core covered with inorganic composition such as zirconium compound, titanium compound, SiO2 and Al2O3. The controlled hydrolysis and heterocoagulation systems were proposed as preparation methods of composite particles. 1st step Cu-CMP Slurry with composite particles as abrasion indicated an excellent dishing, erosion and their over-polish-margin. Particularly these composite particles were useful to prevent increasing scratch on the TEOS and low-k dielectric materials surface in 2nd step CMP process.

Type
Research Article
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Steigerwald, J., Zirpol, R., Murarka, S., Price, D., and Gutmann, R., J. Electrochem. Soc., 141, 2842(1994)10.1149/1.2059241Google Scholar
2. Kawahashi, N., and Matijevic, E., J.Colloid Interface Sci. 138, 534(1990)10.1016/0021-9797(90)90235-GGoogle Scholar
3. Kawahashi, N., and Matijevic, E., J.Colloid Interface Sci. 143, 103(1990)10.1016/0021-9797(91)90442-BGoogle Scholar
4. Kawahashi, N., Persson, C. and Matijevic, E., J.Mater. Chem., 1, 577(1991)10.1039/jm9910100577Google Scholar
5. Shiho, H., Manabe, Y., and Kawahashi, N., J.Mater. Chem., 10, 333(2000)Google Scholar
6. Shiho, H., and Kawahashi, N., J.Colloid Interface Sci., 226, 91(2000)10.1006/jcis.2000.6789Google Scholar
7. Shiho, H., and Kawahashi, N., Colloid Polym. Sci., 278, 270(2000)10.1007/s003960050043Google Scholar
8. Kawahashi, N., and Shiho, H., J.Mater. Chem., 10, 2294(2000)Google Scholar
9. Kokai, J.P. 2000-269170.Google Scholar
10. Kokai, J.P. 2000-204352.Google Scholar
11. Kokai, J.P. 2001-15462.10.1524/hgjb.2001.3.jg.62Google Scholar