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Anion Intercalation and Anion Exchange in Bismuth Compounds

Published online by Cambridge University Press:  11 February 2011

Masamichi Tsuji ,
Makoto Yamaguchi  and
Satoshi Murao
Masamichi Tsuji
Affiliation:
Tokyo Institute of Technology, Research Center for Carbon Recycling and Energy, Tokyo, JAPAN.
Makoto Yamaguchi
Affiliation:
Tokyo Institute of Technology, Research Center for Carbon Recycling and Energy, Tokyo, JAPAN. Institute of Research and Innovation, Kashiwa Laboratory, Chiba, JAPAN.
Satoshi Murao
Affiliation:
Tokyo Institute of Technology, Research Center for Carbon Recycling and Energy, Tokyo, JAPAN. National Institute of Advanced Industrial Science and Technology, Institute for Geo-resources and Environment, JAPAN.
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Abstract

Bismuth nitrate basic, which chemical content is given by 4BiNO3(OH)2.BiO(OH), was studied for anion-intercalation or anion-exchange properties. A crystal structure of the bismuth nitrate basic has not been known. In the present study, its XRD pattern was indexed using a possible orthorhombic system having the lattice parameters of ao=3.021(1) nm, bo=3.029(1) nm and co=0.9572(3) nm. This compound was found to incorporate CH3COO-, halides and several oxyanions including CO32-. Incorporation of these anions by this solid was evidenced by broadening of infrared absorption band by NO3-, suggesting involvement with NO3- ions. Intercalation of CO32- by the bismuth nitrate basic in full extent yielded a bismutite represented by the chemical composition Bi2O2CO3. The bismuth nitrate basic will serve as a new host for anion-intercalation and anion-exchange.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 755: Symposium DD – Solid-State Chemistry of Inorganic Materials IV , 2002 , DD6.10
Copyright
Copyright © Materials Research Society 2003

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References

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