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ATR-FTIR Spectral Investigation of SO2-treated Soda-Lime-Silicate Float Glass

Published online by Cambridge University Press:  10 February 2011

U. Senturk ,
D. H. Lee ,
R. A. Condrate Sr  and
J. R. Varner
U. Senturk
Affiliation:
New York State College of Ceramics at Alfred University, 2 Pine st., Alfred, NY 14802.
D. H. Lee
Affiliation:
New York State College of Ceramics at Alfred University, 2 Pine st., Alfred, NY 14802.
R. A. Condrate Sr
Affiliation:
New York State College of Ceramics at Alfred University, 2 Pine st., Alfred, NY 14802.
J. R. Varner
Affiliation:
New York State College of Ceramics at Alfred University, 2 Pine st., Alfred, NY 14802.
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Abstract

The near-surface infrared spectral changes that occurred on a commercial soda-lime-silicate glass, which was heat treated in SO2/H2O/air atmospheres, were measured, in the region 1200 to 600 cm−1, using attenuated total reflectance Fourier-transform infrared (ATR-FTIR) spectroscopy. Sets of spectra were taken at different angles of incidence of the infrared beam corresponding to successive penetration depths on the surface, hence, giving a surface spectral profile. It was found that the Si-O-Si vibrational band, observed in the region ∼1100 cm−1, is the most affected; with increasing depth the band becomes weaker, depending on the treatment temperature and water content in the treatment atmosphere. The two different sides (the side in contact with the tin bath (tin side) and the opposite side (air side)) were determined to have a different character as a result of the dealkalization treatments.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 407: Symposium M – Disordered Materials and Interfaces-Fractals, structure and Dynamics , 1995 , 337
Copyright
Copyright © Materials Research Society 1996

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References

REFERENCES

1. Coward, J.N. and Turner, W.E S., J. Soc. Glass. Technol., 22, 309 (1938).Google Scholar
2. Williams, H.S., and Weyl, W.A., Glass. Ind. 26, 275 (1945).Google Scholar
3. Weyl, W.A., Glass. Ind. 26, 369 (1945).Google Scholar
4. Douglas, R.W., and Isard, J.O., J. Soc. Glass. Technol., 33, 289 (1949).Google Scholar
5. Hench, L.L. and Clark, D.E., J. Non-Cryst. Solids, 28, 343 (1977).Google Scholar
6. Sharaf, N.A., Brzytwa, S.M., Condrate, R.A. Sr, Hapanowicz, R.P., LaCourse, W.C., and Shen, P., in The Physics of Non-Crystalline Solids, edited by Pye, L.D., LaCourse, W.C., and Stevens, H.V. (Taylor and Francis, London, 1992), p. 236.Google Scholar
7. Uchino, T., Sakka, T., Hotta, K., and Iwasaki, M., J. Amer. Ceram. Soc., 72, 2173 (1989).Google Scholar
8. Harrick, N.J., Internal Reflectence Spectroscopy (Wiley Interscience, New York, 1967).Google Scholar
9. Clark, D.E., Ethridge, E.C., Dilmore, M.F., and Hench, L.L., Glass. Tech., 18, 121 (1977).Google Scholar
10. Hanna, R. and Su, G-J., J. Amer. Ceram. Soc., 47, 597 (1967).Google Scholar
11. Sanders, D.M., Person, W.P., and Hench, L.L., Appl. Spectrosc., 28, 247 (1974).Google Scholar
12. Ferraro, J.R. and Mangnani, M.H., J. Appl. Phys., 43, 4595 (1972).Google Scholar
13. Simon, I. and McMahon, H.O., J. Amer. Ceram. Soc., 36, 160 (1953).Google Scholar
14. Clark, D.E., Dilmore, M.F., Ethridge, E.C., and Hench, L.L., J. Amer. Ceram. Soc., 59, 62 (1976).Google Scholar