Published online by Cambridge University Press: 16 February 2011
We have deposited p+ a-Si,C:H films by reactive magnetron sputtering from boron doped target with 1 at.% B. We have investigated the influence of H2 pressure on the electrical and microstructural properties of the doped a-Si,C:H films. The boron concentration in the film is ∼2–4×1020cm−3. The incorporation of B atoms decreases by a factor of 2 at the highest H2 pressure. We have obtained films of Taue bandgap ∼1.8–1.84eV with dark conductivity 2–8×10− 6Ω−1cm−1, thermal activation energy ∼0.28–0.33eV and νμτe ∼1–3×10−8cm2/V. This result is comparable with glow discharge B doped a-Si,C:H film. We discuss the film Microstructure, as reflected in infra-red & thermal H evolution spectra, vs. the absolute composition of sputtered boron doped a-Si,C:H films.