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Characterization of a Natural Dye by Spectroscopic and Chromatographic Techniques

Published online by Cambridge University Press:  16 August 2012

Y. Espinosa-Morales
Affiliation:
Centro de Investigación en Corrosión, Universidad Autónoma de Campeche. Avda. Agustín Melgar s/n entre Juan de la Barrera y Calle 20. Colonia Lindavista, San Francisco de Campeche, México. e-mail: javreyes@uacam.mx
J. Reyes
Affiliation:
Centro de Investigación en Corrosión, Universidad Autónoma de Campeche. Avda. Agustín Melgar s/n entre Juan de la Barrera y Calle 20. Colonia Lindavista, San Francisco de Campeche, México. e-mail: javreyes@uacam.mx
B. Hermosín
Affiliation:
Instituto de Recursos Naturales y Agrobiología de Sevilla (IRNAS-CSIC), Spain.
J. A. Azamar-Barrios
Affiliation:
CINVESTAV-Unidad Mérida, México.
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Abstract

Natural dyes have been extracted from both plants and animal to give color to textiles and handicrafts. This is the case of purple dye extracted from Justicia spicigera Schldt, an acanthaceae used as a color source since pre-Hispanic period in the Mayan area of Mexico and Central America. Spectroscopic (UV-Vis and FT-IR) and chromatographic (PY-GC/MS) techniques were employed in order to characterize some of their chemical properties. UV-VIS absorption spectra indicates a λmaxpeak at 581 nm, value associated to anthocyanins group under bathochromic effect. On the other hand, a structural characterization realized by FT-IR and Py-GC/MS indicated the presence of polar hydroxibenzoic acids and phenolic compounds which are characteristics of the molecular structure of anthocyanins.

Type
Articles
Copyright
Copyright © Materials Research Society 2012

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References

REFERENCES

Ivic, M., Berguer, M.. in: Ciencia y técnica maya. Ivic de Monterroso, M., Azurdia Bravo, I., Ed., 2008, 101133.Google Scholar
Magaloni, D.. Arqueología Mexicana 93, (2008) 4650.Google Scholar
Magaloni, D., in La pintura mural prehispánica en México: Área Maya. de la Fuente, B. Ed., Instituto de Investigaciones Estéticas UNAM, Mexico, 2001, 155-198.Google Scholar
Cabezas, H.. Unidad geográfica cultural: flora mesoamericana. Universidad Mesoamericana, Guatemala, 2005.Google Scholar
Lock, O., in: Colorantes naturales. Fondo Editorial. Pontificia Universidad Católica de Perú, Lima, 1997.Google Scholar
Espinosa-Morales, Y.. Dissertation thesis. College of Chemistry and Biological Sciences. Universidad Autonoma de Campeche, Campeche, 2010.Google Scholar
Arroyo, E., Falcón, T., Hernández, E., Zetina, S., Nieto, A., Ruvalcaba, J.L.. XVI Century Colonial Panel Paintings from New Spain: Material Reference Standards and Non Destructive Analysis for Mexican Retablos. 9th International Conference on NDT of Art, ART2008, Jerusalem, Israel (2008).Google Scholar
Saíz-Jimenez, C., Haider, K., Meuzelaar, H. L. C.. Geoderm. 22 (1979) 2537.Google Scholar
Lanzarini, G., Morselli, L., Pifferi, G.P., Giumanin, A.G.. J. Chrom. 130 (1997) 261266.Google Scholar
Irwin, W. J. Anal, J.. Appl. Py. 1 (1979) 325.Google Scholar
Ghosal, S., Banerjee, S, Jaiswal, D.. Phytochem. 19 (1980) 332334.Google Scholar
Saiz-Jimenez, C., Hermosin, B., Ortega-Calvo, J. J.. Int. J. Environ. Anal. Chem. 56 (1994) 6371.Google Scholar
Reyes, J., Doctoral thesis. School of Chemistry. Universidad de Sevilla, Sevilla, 2004, 21-23.Google Scholar
Shadkami, F., Helleur, R. J., Cox, R. M., J. Chem. Ecol. 33 (2007) 14671476.Google Scholar
Asen, S., Sterwart, R.N., Norris, K. H. Phytochem. 11(3) (1972) 11391144.Google Scholar
Gris, E., Ferrari, A., Falcao, L., Bordignon, M., Food Chem. (2007) 12891296.Google Scholar
Kanakis, P. A., Tarantilis, M. G., Poliss, S, Diamantoglou, H. A, Tajmir-Riahi, . J. Mol. Struc. 798 (2006) 6974.Google Scholar
Schreiber, H., Swink, A. M., D Godsey, T.. J. Inorg. Biochem. 104 (2010)732739.Google Scholar
Willstater, R., Mieg Liebig, W.. Ann Chem. 408 (1915) 327.Google Scholar
Yoshimata, K., Hayashi, K.. Biol. Mag. Tokio. 87 (1974) 3340.Google Scholar
Guerrero, I., Lopez, E., Armenta, R.. Pigmentos. in: Quimica de los Alimentos. Badui, Salvador Ed. Fourth Edition. volume II, Pearson Educacion, México, 2006, 401439.Google Scholar
Myjavcová, R., Marhol, P., Kren, V., Simanek, V., Ulrichová, J., Palíková, I., Papouskova, B., Lemr, K., Bedñar, P., J. of Chrom A 1217 (2010) 79327941.Google Scholar
Satapathy, A.K., Gunasekaran, G., Sahoo, S.C., Amit, K., Rodrigues, P.V., Corros. Sci. 51 (2009) 28482856.Google Scholar
Torres, O., Santafé, G., Angulo, A., Villa, H., Zuluaga, J., Doria, M.. Sci. Tech. XIII 3 (2007) 333336.Google Scholar
Phillip, R. P., Applications and spectra. Elsevier, Amsterdam, 1985, 88-91.Google Scholar
Isaza, J. H., Orozco, L. M., Zuleta, L. M., Rivera, D. A., Tapias, L. J., Veloza, L. A., Ramirez, L. S.. Sci. Tech. XIII 33 (2007) 359362.Google Scholar
Füzfai, Z., Molnár-Perl, I.. J. Chrom. A 1149 (2007) 88101.Google Scholar
Nolte, C. G., Schauer, J. J., Cass, G. R., Smoneit, B. R. T.. Environ. Sci. Tech. 35 (2001)19121919.Google Scholar
Fernández, M. P., Watson, P. A., Breuil, C., J. Chrom. A. 922 (2001) 225233.Google Scholar