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Conductive Polymer / Superconductor Sandwich Structures

Published online by Cambridge University Press:  21 February 2011

Steven G. Haupt ,
Jianai Zhao ,
Rung-Kuang Lo ,
Ji-Ping Zhou  and
John T. McDevitt
Steven G. Haupt
Affiliation:
Department of Chemistry & Biochemistry, The University of Texas at Austin, Austin, TX 78712.
Jianai Zhao
Affiliation:
Department of Chemistry & Biochemistry, The University of Texas at Austin, Austin, TX 78712.
Rung-Kuang Lo
Affiliation:
Department of Chemistry & Biochemistry, The University of Texas at Austin, Austin, TX 78712.
Ji-Ping Zhou
Affiliation:
Department of Chemistry & Biochemistry, The University of Texas at Austin, Austin, TX 78712.
John T. McDevitt
Affiliation:
Department of Chemistry & Biochemistry, The University of Texas at Austin, Austin, TX 78712.
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Abstract

Methods for characterizing the interface of conductive polymer/high-Tc superconductor sandwich structures are reported. Electrochemical procedures, such as cyclic voltammetry and chronoamperometry, are utilized to deposit conductive polymers directly onto bulk ceramic and thin film samples of YBa2Cu3O7-δ. Moreover, similar methods are utilized to cycle the polymer structures between their neutral (non-conductive) and oxidized (conductive) forms. Through changes in the polymer doping level, the superconducting properties of the high-Tc component can be modulated in a controllable and reproducible fashion. This paper focuses on an analysis of conductive polymer/superconductor interface phenomena as explored by electrochemical, resistivity vs. temperature and contact resistance measurements.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 318: Symposium Ca – Interface Control of Electrical, Chemical, and Mechanical Properties , 1993 , 671
Copyright
Copyright © Materials Research Society 1994

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References

REFERENCES

1 a) Haupt, S.G., Riley, D.R., Jones, C.T., Zhao, J., McDevitt, J.T., J. Am. Chem. Soc. 115, 1196–1198 (1993). b) J.T. McDevitt, S.G. Haupt, D.R. Riley, J. Zhao, and C.T. Jones, MRS Symposium Series; Volume 304 - Polymer/Inorganic Interfaces; San Francisco, CA, April (1993), accepted.Google Scholar
2 a) Kaneto, K. and Yoshino, K., Jpn. J. Appl. Phys. 26 (11), L1842 L1844 (1987). b) J.T. McDevitt, R.L. McCarley, E.F. Dalton, R. Gollmar, R.W. Murray, J.P. Collman, G.T. Yee, and W.A. Little, in Chemistry of High-Temperature Superconductors II . edited by , D.L. Nelson, and T.F. George ), ACS Symposium Series 377, (Washington, D. C: American Chemical Society Press, 1988), Chapter 17. c) J.G. Osteryoung, L.J. Magee, and R.T. Carlin, J. Electrochem. Soc. 135 (10), 2653-2654 (1988).Google Scholar
3 Izakovich, E.N., Geskin, V.M. and Stepanov, S.V., Synth. Metals 46, 71–77 (1992).Google Scholar
4 Barns, R. L. and Laudise, R. A., Appl. Phys. Lett. 51, 1373 (1987).Google Scholar
5 Bansol, N. P. and Sandkuhl, A. L., Appl. Phys. Lett. 52, 323 (1988).Google Scholar
6 Yan, M. F., Barns, R. L., O'Bryan, H. M., Gallagher, P. K. and Sherwood, R. C., Jin, S., Appl. Phys. Lett. 51, 532 (1987).Google Scholar
7 a) McDevitt, J.T., Riley, D.R., and Haupt, S.G., Anal. Chem. 65, 535A–545A (1993). b) S.R. Peck, L.S. Curtin, J.T. McDevitt, R.W. Murray, J.P. Collman, W.A. Little, T. Zetterer, H.M. Duan, C. Dong and A.M. Hermann, J. Am. Chem. Soc. 114, 6771-6775(1992).Google Scholar
8 Handbook of Conducting Polymers, edited by. Skothheim, T. A., (Marcel Dekker, Inc., New York, 1986).Google Scholar
9 Sugimoto, R., Takeda, S., Gu, H., Yoshino, K., Chem. Express 1, 635–638 (1986).Google Scholar
10 a) Meissner, H., Phys. Rev. 117 (3), 672–680 (1960). b) P. Hilsch, Z. Phys. 167, 511-524(1962).CrossRefGoogle Scholar
11 Fiory, A.T., Hebard, A.F., Eick, R.H., Mankiewich, P.M., Howard, R.H., and O'Malley, M.L., Phys. Rev. Lett. 65, 3441 (1990).Google Scholar
12 Kabasawa, U., Asano, K., and Koayashi, T., Jpn. J. Appl. Phys. 29, L86 (1990).Google Scholar
13 Mannhart, J., Bednorz, J.G., Miiller, K.A., and Schlom, D.G., Z. Phys. B. 83, 307 (1991).Google Scholar
14 Haupt, S.G.; Riley, D.R.; Zhao, J., and McDevitt, J.T., J. Phys. Chem. 97, 7796–7799 (1993).CrossRefGoogle Scholar