Hostname: page-component-78c5997874-ndw9j Total loading time: 0 Render date: 2024-11-13T09:28:28.481Z Has data issue: false hasContentIssue false

Control of the Surface Properties of Microfludic Devices by Using Polyelectrolyte Multilayer Coatings

Published online by Cambridge University Press:  01 February 2011

Hyun Park
Affiliation:
moto38@nate.com, Chungnam National University, Polymer Science and Engineering, Daejeon, Korea, Republic of
Yoo-Jin An
Affiliation:
m_248655@naver.com, Chungnam National University, Polymer Science and Engineering, Daejeon, Korea, Republic of
Sung Yun Yang
Affiliation:
sungyun@cnu.ac.kr, Chungnam National University, Polymer Science and Engineering, Daejeon, Korea, Republic of
Get access

Abstract

Recently, more studies have been conducted in chemical and biological applications using microfluidic or nanofluidic devices.1 Polymer-based materials have been newly developed in this field due to the great needs of easy processing, cost-effectiveness and clarity for the material. However, it is still challenging to control of the surface properties of these devices on demand. Especially, for biological analysis or detection, micro-fluidics should handle aqueous samples but, most of the current materials in use for micro-fluidic devices are relatively hydrophobic (such as PDMS, PMMA and cyclo-olefin-co polymer, etc). Therefore, they usually need an extra assistance rather than a capillary force to flow the aqueous samples. In this paper, we utilized layer-by-layer deposition of polymer to modify the surface of the micro-channel of the device in order to control surface properties of the micro-channel. We have been studied polyelectrolyte multilayer(PEM) coatings to control surface wettability of the open structures and found various hydrophilic films. Here we demonstrate polyelectrolyte multilayer film as an effective coating for inner surface of micro-fluidic devices to lowering the water contact angle, so that the aqueous fluid will travel smoothly with the channels. Compared to the other surface treatment method such as base cleaning or plasma irradiation, the PEM coating exhibit highly sustained water wettability. Polyelectrolytes used for this study are weak polyelectrolytes including biodegradable polymer such as poly(hyaluronic acid) (HA) for future biological applications.

Type
Research Article
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1 Whitesides, G. M., Nature, 442, 27 (2006).Google Scholar
2 Decher, G., Hong, J. D., Makromol. Chem. Macromol. Symp. 16, 321 (1991)Google Scholar
3 Shiratori, S., Rubner, M. F., Macromlecules 33, 4213 (2000).Google Scholar
4 Dubas, S. T., Schlenoff, J. B., Langmuir 17, 7725 (2001).Google Scholar
5 Yang, S. Y., Rubner, M. F., J. Am. Chem. Soc., 124, 2100 (2002).Google Scholar
6 Berg, M. C., Yang, S. Y., Hammond, P. T., Rubner, M. F., Langmuir, 20, 1362 (2004).Google Scholar
7 Wang, T. C., Chen, B., Rubner, M. F., Cohen, R. E., Langmuir 17, 6610 (2001).Google Scholar
8 Yang, S. Y., Seo, J. Y., J. Colloids and surfaces A: Physicochem Eng. Aspects, 313314, 526 (2008).Google Scholar
9 Jeong, H.-J., Pyun, W.-H., Yang, S. Y., Macromol. Rapid Comm. 30(13), 1109 (2009).Google Scholar
10 Yang, S. Y., Kim, D.-Y., Jeong, S.-M., Park, J. W., Macromol. Rapid Comm. 29(9), 729 (2008).Google Scholar