Hostname: page-component-78c5997874-s2hrs Total loading time: 0 Render date: 2024-11-10T05:48:20.325Z Has data issue: false hasContentIssue false
  • English
  • Français

Controlled Conductive Polymer Coating on Wood Microfibers via Layer-by-layer Nanoassembly

Published online by Cambridge University Press:  01 February 2011

Mangilal Agarwal ,
John McDonald ,
Yuri Lvov  and
Kody Varahramyan
Mangilal Agarwal
Affiliation:
mag015@latech.edu, Louisiana Tech University, Institute for Micromanufacturing, 911 Hergot Ave, Ruston, LA, 71272, United States, 318-614-5430, 318-257-5104
John McDonald
Affiliation:
mcdonald@coes.latech.edu, Louisiana Tech University, Institute for Micromanufacturing, 911 Hergot Ave, Ruston, LA, 71272, United States
Yuri Lvov
Affiliation:
ylvov@latech.edu, Louisiana Tech University, Institute for Micromanufacturing, 911 Hergot Ave, Ruston, LA, 71272, United States
Kody Varahramyan
Affiliation:
kody@latech.edu, Louisiana Tech University, Institute for Micromanufacturing, 911 Hergot Ave, Ruston, LA, 71272, United States
Get access

Abstract

This paper reports on layer-by-layer (LbL) self-assembly of poly (3, 4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT-PSS) conducting polymer on lignocellulose wood microfibers to make conducting paper. Polycation such as poly(allylamine hydrochloride) (PAH) was used with polyanionic PEDOT-PSS to construct the multilayers. The physical characterization of the microfiber was done using roughness step tester (RST) and surface profilometer (TENCOR). Thickness of the coated film was estimated using a quartz crystal micro-balance. Current – Voltage characterization was performed using a Keithley measurement system after each self-assembly of PEDOT-PSS to study the electrical properties of the coated film. It was observed that the conductivity of the microfiber was proportional to the number of polyelectrolyte bilayers deposited. The measured conductivities ranged from (1 to 5) × 10-3 Scm-1 to 1 to 10 Scm-1 for different bilayers of PEDOT-PSS on wood microfibers. It was also observed that the conductivity of the nano-coated fibers is dependent upon the salt concentration used in PAH polycations to from the multilayer. In this work we are developing scale integration from nano, to micro and macro (nanocoating-microfibers-macropaper). The results obtained show great promise for the development of smart paper technology and its contribution to the economic development of the nation.

Keywords

coatingnanoscalepolymer
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 920: Symposium S – Smart Nanotextiles , 2006 , 0920-S03-05
Copyright
Copyright © Materials Research Society 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Casey, J. P., in Pulp and Paper: Chemistry and Chemical Technology, 3rd ed. (John Wiley & Sons, 1981).Google Scholar
2. Synovec, M., Shearin, R., and Pauksta, P., Technical Association of the Pulp and Paper Industry Journal 79(5), 55, 1996.Google Scholar
3. Zheng, Z., McDonald, J., Khillan, R., Grozdits, G., and Lvov, Y., Journal of Nanoscience and Nanotechnology 6, 624, 2006.Google Scholar
4. Varahramyan, K., and Lvov, Y., 3rd International Symposium on Nanomanufacturing, Cypress, November, 2005.Google Scholar
5. Iler, R. K., Journal of Colloid Interfacial Science 21, 569, 1966.Google Scholar
6. Lvov, Y., Decher, G., and Möhwald, H., Langmuir 9, 481, 1993.Google Scholar
7. Lvov, Y., Katsuhiko, A., Mitsuhiko, O., Ichinose, I., and Kunitake, T., Langmuir 13, 6195, 1997.Google Scholar
8. Ariga, K., Lvov, Y., and Kunitake, T., Journal of the American Chemical Society 119, 2224, 1997.Google Scholar
9. Fang, M., Grant, P., McShane, M., Sukhorukov, G., Golub, V., and Lvov, Y., Langmuir 18, 6338, 2002.Google Scholar
10. Srivastava, R., Brown, J. Q., Zhu, H., and McShane, M., Biotechnology and Bioengineering 91, 124, 2005.Google Scholar
11. Zhu, H., and McShane, M., Journal of the American Chemical Society 127, 13448, 2005.Google Scholar
12. Paloniemi, H., Lukkarinen, M., Aaritalo, T, Areva, S., Leiro, J., Heinonen, M., Haapakka, K., and Lukkari, J., Langmuir 22, 74, 2006.Google Scholar