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Conversion of an Aurivillius Phase Bi2SrNaNb3O12 into Its Protonated Form via Treatment with Various Mineral Acids

Published online by Cambridge University Press:  18 March 2011

Masashi Shirata ,
Yu Tsunoda ,
Wataru Sugimoto  and
Yoshiyuki Sugahara
Masashi Shirata
Affiliation:
Department of Applied Chemistry, School of Science and Engineering, Waseda University, Shinjuku-ku, Tokyo 169-8555, JAPAN
Yu Tsunoda
Affiliation:
Department of Applied Chemistry, School of Science and Engineering, Waseda University, Shinjuku-ku, Tokyo 169-8555, JAPAN
Wataru Sugimoto
Affiliation:
Department of Fine Materials Engineering, Faculty of Textile Science and Technology, Shinshu University, Ueda, Nagano, 386-8567, JAPAN
Yoshiyuki Sugahara
Affiliation:
Department of Applied Chemistry, School of Science and Engineering, Waseda University, Shinjuku-ku, Tokyo 169-8555, JAPAN
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Abstract

A protonated form of a layered perovskite was prepared from an Aurivillius phase Bi2SrNaNb3O12via acid treatments, and the effect of the type of mineral acids was investigated. The treatment with HX (X = Cl, Br, I) resulted in the formation of a protonated form H1.8[Sr0.8Bi0.2NaNb3O10], while no reactions were observed for HNO3 and H2SO4 under the present experimental conditions. All the products obtained by HX-treatments exhibited layered structures and the structures of the perovskite-like slabs were preserved.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 658: Symposium GG – Solid-State Chemistry of Inorganic Materials III , 2000 , GG6.24
Copyright
Copyright © Materials Research Society 2001

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References

REFERENCES

1. Gopalakrishnan, J., Rev. Solid State Sci. 1, 515 (1988).Google Scholar
2. Dion, M., Ganne, M. and Tournoux, M., Mater. Res. Bull. 16, 1429 (1981).Google Scholar
3. Jacobson, A. J., Johnson, J. W. and Lewandowski, J. T., Inorg. Chem. 24, 3727 (1985).Google Scholar
4. Ruddlesden, S. N. and Popper, P., Acta Crystllogr. 10, 538 (1957).Google Scholar
5. Ruddlesden, S. N. and Popper, P., Acta Crystllogr. 11, 54 (1958).Google Scholar
6. Gopalakrishnan, J., Bhat, V. and Raveau, B., Mater. Res. Bull. 22, 413 (1987).Google Scholar
7. Dion, M., Ganne, M. and Tournoux, M., Rev. Chim. Miner. 23, 61 (1986).Google Scholar
8. Jacobson, A. J., Lewandowski, J. T. and Johnson, J. W., J. Less-Common Met. 116, 137 (1986).Google Scholar
9. Ebina, Y., Tanaka, A., Kondo, J. N. and Domen, K., Chem. Mater. 8, 2534 (1996).Google Scholar
10. Subramanian, M. A., Gopalakrishnan, J. and Sleight, A. W., Mater. Res. Bull. 23, 837 (1988).Google Scholar
11. Jacobson, A. J., Johnson, J. W. and Lewandowski, J. T., Mater. Res. Bull. 22, 45 (1987).Google Scholar
12. Olivier, P. J. and Mallouk, T. E., Chem. Mater. 10, 2585 (1998).Google Scholar
13. Rao, C. N. R. and Raveau, B., Transition Metal Oxide, 2nd edition, (Wiley-VCH, 1998) pp.74-75.Google Scholar
14. Suzuki, M., Nagasawa, N., Machida, A. and Ami, T., Jpn. J. Appl. Phys. 35, L564 (1996).Google Scholar
15. Sugimoto, W., Shirata, M., Sugahara, Y. and Kuroda, K., J. Am. Chem. Soc. 121, 11601 (1999).Google Scholar
16. Gopalakrishnan, J., Sivakumar, T., Ramesha, K., Thangadurai, V. and Subbanna, G. N., J. Am. Chem. Soc. 122, 6237 (2000).Google Scholar
17. , Ismunandar and Kennedy, B. J., J. Solid State Chem. 126, 135 (1996).Google Scholar
18. Izumi, F., Rietveld Analysis Programs RIETAN and PREMOS and Special Applications, Rietveld Analysis, ed. Young, R. A., (Oxford University Press, 1993) pp.236–253.Google Scholar
19. Kim, Y. I. and Izumi, F., J. Ceram. Soc. Jpn. 102, 401 (1994).Google Scholar
20. Blake, S. M., Falconer, M. J., McCreedy, M. and Lightfoot, P., J. Mater. Chem. 7, 1609 (1997).Google Scholar
21. Bleza, M. A., Morando, P. J. and Regazzoni, A. E., Chemical Dissolution of Metal Oxides, (CRC Press, 1994) pp.172–177.Google Scholar