The Corrosion Phenomena in The Coin Cell Br2325 of The “Superstoichiometric Fluorocarbon - Lithium” System

Extract

It was noted at the earlier study and at the longer observations of the novel various types of superstoichiometric fluorocarbon materials CF_1+x, where x = 0.1–0.33 (FCM) and their behavior, that despite of their known hygroscopity during a storage of samples in laboratory and technological utensils nevertheless occurs an appreciable sorption of atmospheric moisture. The color of samples does not change but sometimes there is appears a smell of hydrogen fluoride and even corrosion of glasswares at a long storage. On the basis of these facts was assumed that at a long storage the slow reactions of HF producing with a sorption moisture can proceed. This phenomena is necessary to take into account for successful manufacturing of long life lithium cells based on superstoichiometric fluorocarbon composite cathodes (FCC).