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Crystal Chemistry and Electronic Properties of the N = 2 Ruddlesden-Popper Manganates: Unconventional CMR Materials

Published online by Cambridge University Press:  15 February 2011

P. D. Battle ,
S. J. Blundell ,
D. E. Cox ,
M. A. Green ,
J. E. Millburn ,
P. G. Radaelli ,
M. J. Rosseinsky ,
J. Singleton ,
L. E. Spring  and
J. F. Vente
P. D. Battle
Affiliation:
Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QR, U.K.
S. J. Blundell
Affiliation:
Department of Physics, Clarendon Laboratory, University of Oxford, Parks Road, Oxford OX1 3PU, U.K.
D. E. Cox
Affiliation:
Department of Physics, Brookhaven National Laboratory, Upton, NY 11973, U.S.A.
M. A. Green
Affiliation:
Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QR, U.K.
J. E. Millburn
Affiliation:
Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QR, U.K.
P. G. Radaelli
Affiliation:
Institut Laue-Langevin, P.O. Box 156, 38042 Grenoble Cedex 9, France
M. J. Rosseinsky
Affiliation:
Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QR, U.K.
J. Singleton
Affiliation:
Department of Physics, Clarendon Laboratory, University of Oxford, Parks Road, Oxford OX1 3PU, U.K.
L. E. Spring
Affiliation:
Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QR, U.K.
J. F. Vente
Affiliation:
Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QR, U.K.
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Abstract

The crystallography and electronic properties of the Ln2-xSr1+xMn2O7 manganese oxides adopting the n = 2 Ruddlesden-Popper (RP) structure are discussed, focusing on the structural phase diagrams and electronic properties in the vicinity of the Mn +3.5 oxidation state and in particular the ease of synthesis of single phases of these materials.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 453: Symposium R – Solid State Chemistry of Inorganic Materials , 1996 , 331
Copyright
Copyright © Materials Research Society 1997

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References

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