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Published online by Cambridge University Press: 21 February 2011
Crystallographic defects which form during growth of CVD diamond were studied and their effect on the surface structure of the growing wafer evaluated. The most abundant defects are β=3 twins boundaries whose density is very high at the nucleation side and as low as one twin per 10 /μm at the growth surface. The intersection of these twin boundaries with one another results in a formation of higher order twin boundaries. β=9 as well as β=27 and β=81 boundaries have been analyzed. The surface crystallography of optical quality diamond wafers reveals the role of β=3 twins in promoting fast growth.