Hostname: page-component-78c5997874-ndw9j Total loading time: 0 Render date: 2024-11-14T19:45:25.108Z Has data issue: false hasContentIssue false
  • English
  • Français

Effect Co- and Sc- Doping on the Functional Properties of Nanocrystalline Powders and Thin Films of ZnO

Published online by Cambridge University Press:  01 February 2011

Marco A Galvez ,
Oscar Perales-Perez  and
Surinder P Singh
Marco A Galvez
Affiliation:
marco.galvez@upr.edu, University of Puerto Rico Mayaguez, Physics, Mayaguez, Puerto Rico
Oscar Perales-Perez
Affiliation:
operalesperez@yahoo.com, University of Puerto Rico, Department of Engineering Science and Materials, sTEFANI bUILDING 601, Mayaguez, Mayaguez, 00680, Puerto Rico
Surinder P Singh
Affiliation:
surinder.singh@upr.edu, University of Puerto Rico Mayaguez, Engineering science and Materials, Mayaguez, Mayaguez, 00681, Puerto Rico
Get access

Abstract

A modified sol-gel approach to synthesize well-crystallized pure and doped ZnO nanocrystalline powders and thin films has been developed. The attachment of ZnO films onto quartz substrates was optimized by selecting suitable organic agents to control the viscosity of precursor solutions. Thermo-gravimetric analyses on pure and doped precursor solids suggested the need for annealing temperatures above 400 °C to assure the effective crystallization of the oxide phase. The average crystallite size in powders and thin films varied from 25.9 nm to 33.7 nm when pure ZnO films were annealed for 1 hour in the 450 °C - 600 °C range. The average crystallite size ranged between 30 nm and 33 nm in the presence of cobalt (5 at%) and decreased from 33.7 nm to 21.1 nm when scandium ions was used in the 0.0 at% - 10 at% range under similar annealing conditions. UV-vis measurements showed a sharp exciton peak centered at 370 nm whereas photoluminescence analyses detected the characteristic ZnO emission band in the UV region. No photoluminescence band in the visible region, usually attributed to defect states in ZnO, was observed in our measurements. Magnetization measurements revealed a weak ferromagnetism in Co-doped ZnO whereas a clear diamagnetism was evident in the Sc-doped sample.

Keywords

thin filmsol-gelspintronic
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1256: Symposium N – Functional Oxide Nanostructures and Heterostructures , 2010 , 1256-N11-23
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Sato, K. Katayama-Yoshida, H., J. Appl Phys B 308–310 (2001), 904–907.Google Scholar
[2] Pan, F. Song, C. et al. , Materials Science and Engineering R 62 (2008), 1–35.Google Scholar
[3] Qi, Jing, Gao, Daqiang et al. Appl Phys A 100 (2010) 79–82.Google Scholar
[4] Wolf, S. A. Awschalom, D. D. et al. Science, 294, (2001) 1488.Google Scholar
[5] Yoon, K.H. Choi, J.W. Lee, D.H. Thin Solid Films 302 (1997) 116.Google Scholar
[6] Ogawa, M.F. Natsume, Y. et al. J. Mater. Sci. Lett 9, (1990), 1351–1353.Google Scholar
[7] Hu Roy, J. Gordon, G. J. Appl. Phys. 71, (1992), 880.Google Scholar
[8] Kim, H. Horwitz, J.S. Qadri, S.B. Chrisey, D.B. Thin Solid Films 420–421 (2002) 107.Google Scholar
[9] Lee, J.H. Ko, K.H. Park, J.L. J. Cryst. Growth 247 (2003) 119.Google Scholar
[10] Song, D. Windenborg, P. Chin, W. Aberle, A. Sol. Energy Mater. Sol. Cells 73 (2002) 269.Google Scholar
[11]. Burstein, E. Phys. Rev. 25 (1982) 7826.Google Scholar
[12]. Lu, J.J. Lu, Y.M. Tasi, S.I. et al. Optical Materials 29 (2007) 1548–1552 Google Scholar
[13]Bylander, E.G. J. Appl. Phys. 49 (1978) 1188.Google Scholar
[14] Liu, M. Kitai, A.H. Mascher, P. J. Lumin. 54 (1992) 35.Google Scholar
[15] Sharma, Ruchika, Applied Surface Science 255 (2009) 5781–5788.Google Scholar
[16] Kuo, Shou-Yi, Lai, Fang-I et al. Japanese J. Appl. Phys 45, No. 4B, (2006) 3662–3665.Google Scholar
[17]. Shionoya, S. and Yen, W.M. Phosphor Handbook, CRC Press, Boca Raton, Florida 1999.Google Scholar
[18]. Venkatesan, M. Fitzgerald, C. B. et al. Phys. Rev. Lett 93 (2004), 177206.Google Scholar