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Effect of Water Vapor and SOx in Air on the Cathodes of Solid Oxide Fuel Cells

Published online by Cambridge University Press:  01 February 2011

Seon Hye Kim ,
Toshihiro Ohshima ,
Yusuke Shiratori ,
Kohei Itoh  and
Kazunari Sasaki
Seon Hye Kim
Affiliation:
hye@mech.kyushu-u.ac.jp, Kyushu University, Faculty of Engineering, Motooka 744, Nishi-ku, Fukuoka, 819-0395, Japan, +81-92-802-3094, +81-92-802-3094
Toshihiro Ohshima
Affiliation:
oshima@mech.kyushu-u.ac.jp, Kyushu University, Faculty of Engineering, Fukuoka, 819-0395, Japan
Yusuke Shiratori
Affiliation:
y-shira@mech.kyushu-u.ac.jp, Kyushu University, Faculty of Engineering, Fukuoka, 819-0395, Japan
Kohei Itoh
Affiliation:
kohei@mech.kyushu-u.ac.jp, Kyushu University, Faculty of Engineering, Fukuoka, 819-0395, Japan
Kazunari Sasaki
Affiliation:
sasaki@mech.kyushu-u.ac.jp, Kyushu University, Faculty of Engineering, Fukuoka, 819-0395, Japan
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Abstract

Ambient air is used as an oxygen source in SOFCs to be commercialized. Various chemical species which can lead to poisoning of SOFC cathodes are included as minor constitutions in air, such as water vapor, SOx, NOx and NaCl etc. However, their effects on the cathode performance have not yet well known, even though they are expected to cause a degradation of the electrode performance and to reduce the long-term durability of SOFCs. Therefore, in this study, we focused on the poisoning caused by water vapor and SOx in the oxygen source to clarify their effects on SOFCs performances and to reveal the degradation mechanism of cathodes. SOFCs with typical electrolyte-supported structure were used in this work, which were composed with ScSZ (10 mol% Sc2O3, 1mol% CeO2, 89 mol% ZrO2) plate with the thickness of 200 µm as electrolyte, NiO-ScSZ (mixture of 56 wt% NiO and 44 wt% ScSZ) porous layer as anode, and two cathode layers of LSM ((La0.8Sr0.2)0.98MnO3) and LSM-ScSZ (mixture of 50 wt% LSM and 50 wt% ScSZ). Power generation characteristics of the cells had been analyzed by measuring cell voltage at a constant current density (200 mA/cm2) and by comparing changes in cell impedance, upon supplying the artificially-contaminated air with water vapor or SOx, to the SOFC cathodes at various operational temperatures. High-resolution FESEM (S-5200, Hitachi) was used to analyze microstructural changes caused by the impurities. Mg Kα radiation from a monochromatized X-ray source was used for XPS measurements (ESCA-3400, KRATOS). AC impedance was measured at various temperatures under the open circuit voltage condition by an impedance analyzer (Solatron 1255B/SI 1287, Solatron), in a frequency range from 0.1 to 105 Hz with an amplitude of 10 mV.

Keywords

energy-storagesurface reactionx-ray photoelectron spectroscopy (XPS)
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1041: Symposium R – Life-Cycle Analysis for New Energy Conversion and Storage Systems , 2007 , 1041-R03-10
Copyright
Copyright © Materials Research Society 2008

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