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Excited-State Intramolecular Proton Transfer in Polymers

Published online by Cambridge University Press:  10 February 2011

Richard M. Tarkka  and
Samson A. Jenekhe
Richard M. Tarkka
Affiliation:
Department of Chemical Engineering and Center for Photoinduced Charge Transfer University of Rochester, Rochester, New York 14627-0166
Samson A. Jenekhe
Affiliation:
Department of Chemical Engineering and Center for Photoinduced Charge Transfer University of Rochester, Rochester, New York 14627-0166
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Abstract

Excited state intramolecular proton transfer (ESIPT) has been demonstrated in new intramoleculary hydrogen bonded (IHB) polymers of interest as photostabilizers, triplet quenchers, photochromic materials, laser dyes and electroluminescent materials. The new IHB polymers containing the 2-(2-hydroxyphenyl)benzoxazole moiety in the main chain were used to explore the effects of polymer structure, extended conjugation and competition with excimer formation on the ESIPT process. It was found that polymer structure, and particularly extent of conjugation, affects an IHB polymer's ability to exhibit ESIPT.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 413: Symposium W – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials III , 1995 , 97
Copyright
Copyright © Materials Research Society 1996

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References

REFERENCES

1. Wiechman, M., Port, H., Laemer, F., Frey, W. and Elsaesser, T., Chem. Phys. Lett., 165, 28 (1990).Google Scholar
2. H.K Sinha and Dogra, S.K., Chem. Phys., 102, 337 (1986).Google Scholar
3. Rodriguez-Preito, M.F., Nickel, B., Grellman, K.H. and Mordzinski, A., Chem. Phys. Lett., 146, 567 (1988).Google Scholar
4. Becker, R.S., Lenoble, C. and Zein, A., J. Chem. Phys., 91, 3509 (1987).Google Scholar
5. Barbara, P.F., Walsh, P.K. and Brus, L.E., J. Phys. Chem., 93, 29 (1989).Google Scholar
6. See the special issues: Chem. Phys., 136, pp. 153–360 (1989); J. Phys. Chem., 95, pp. 10215–10524 (1991).Google Scholar
7. Nir, Z. and Vogl, O., J. Polym. Sci. Polym. Chem. Ed., 20, 2735 (1982).Google Scholar
8. O'Connor, D.B., Scott, G.W., Coulter, D.R., Gupta, A., Webb, S.P., Yeh, S.W. and Clark, J.H., Chem. Phys. Lett., 121, 417 (1985).Google Scholar
9. Khan, A.U. and Kasha, M., Proc. Natl. Acad. Sci. USA, 80, 1767 (1983).Google Scholar
10. Brucker, G.A., Swinney, T.C. and Kelley, D.F., J. Phys. Chem., 95, (1991) 3190.Google Scholar
11. Acuna, A.U., Amat-Guerri, F., Costela, A., Douhal, A., Figuera, J.M., Florido, F. and Sastre, R., Chem. Phys. Lett., 187, 98 (1991).Google Scholar
12. Ferrer, M.L., Acuna, A.U., Amat-Guerri, F., Costela, A., Figuera, J.M., Florido, F. and Sastre, R., Appl. Opt., 33, 2266 (1994).Google Scholar
13. (a). Jenekhe, S.A. and Osaheni, J.A., Science, 265, 765 (1994). (b). J.A. Osaheni and S.A. Jenekhe, J. Am. Chem. Soc., 117, 7398 (1995).Google Scholar
14. Osaheni, J.A. and Jenekhe, S.A., Macromolecules, 26, 4726 (1993).Google Scholar
15. Burroghes, J.H., Bradley, D.D.C., Brown, A.R., Marks, R.N., Mackay, K., Friend, R.H., Burn, P.L. and Holmes, A.B., Nature, 347, 539 (1990).Google Scholar
16. Jenekhe, S.A., Johnson, P.O. and Agrawal, A.K., Macromolecules, 22, 3216 (1989).Google Scholar
17. Wolfe, J.F in Encyclopedia of Polymer Science and Engineering. Volume 11; Wiley, New York, 1988, pp. 601–635.Google Scholar
18. Miura, Y., Torres, E. and Panetta, C.A., J. Org. Chem., 53, 439 (1988).Google Scholar
19. Schmitt, R.J., Ross, D.S., Hardee, J.R. and Wolfe, J.F., J. Org. Chem., 53, 5568 (1988).Google Scholar
20. Doxsee, K.M., Feigel, M., Stewart, K.D., Canary, J.W., Knobler, C.B. and Cram, D.J., J. Am. Chem. Soc., 109, 3098 (1987).Google Scholar
21. Reinhardt, B.A., Polym. Commun., 31, 453 (1990).Google Scholar
22. Jenekhe, S.A., Johnson, P.O. and Agrawal, A.K., Macromolecules, 22, 3216 (1989).Google Scholar
23. Jenekhe, S.A. and Johnson, P.O., Macromolecules, 23, 4419 (1990).Google Scholar
24. Woolfe, G.J., Melzig, M., Schneider, S. and Dorr, F., Chem. Phys., 77, 213 (1983).Google Scholar
25. Elsaesser, T. and Schmetzer, B., Chem. Phys. Lett., 140, 293 (1987).Google Scholar
26. Hammond, G.S., J. Am. Chem. Soc., 77, 334 (1955).Google Scholar