Hostname: page-component-78c5997874-xbtfd Total loading time: 0 Render date: 2024-11-14T06:52:02.567Z Has data issue: false hasContentIssue false
  • English
  • Français

Fabrication of Cu2ZnSn(S,Se)4 solar cells by printing and high-pressure sintering process

Published online by Cambridge University Press:  28 August 2013

Feng Gao ,
Tsuyoshi Maeda  and
Takahiro Wada
Feng Gao
Affiliation:
Department of Materials Chemistry, Ryukoku University, Seta, Otsu 520-2194, Japan
Tsuyoshi Maeda
Affiliation:
Department of Materials Chemistry, Ryukoku University, Seta, Otsu 520-2194, Japan
Takahiro Wada
Affiliation:
Department of Materials Chemistry, Ryukoku University, Seta, Otsu 520-2194, Japan
Get access

Abstract

We fabricated Cu2ZnSn(SxSe1-x)4 (CZTSSe) solar cells by a printing and high-pressure sintering (PHS) process. First, the CZTSSe solid solution powders were synthesized by heating the elemental mixtures at 550oC for 5 h in an N2 gas atmosphere. We fabricated CZTSSe films by a printing and high-pressure sintering (PHS) process. The obtained dense CZTSSe film was post-annealed at 550oC for 10 min under an N2 +5% H2S gas atmosphere. We fabricated CZTSSe solar cells with the device structure of Ag/ITO/i-ZnO/CdS/CZTSSe/Mo/soda-lime glass. The CZTSSe solar cell showed an efficiency of 2.1%, with Voc of 272 mV, Jsc of 18.0 mA/cm2 and FF of 0.44.

Keywords

thin filmphotovoltaichot pressing
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1538: Symposium C – Compound Semiconductors: Thin-Film Photovoltaics, LEDs and Smart Energy Controls , 2013 , pp. 179 - 183
Copyright
Copyright © Materials Research Society 2013 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Jackson, P., Hariskos, D., Lotter, E., Paetel, S., Wuerz, R., and Menner, R., Prog. Photovolt. Res. Appl. 19, 894 (2011).CrossRefGoogle Scholar
Friedlmeier, TM., Wieser, N., Walter, T., Dittrich, H., and Schock, HW., Proceedings of the 14th European Photovoltaic Specialists Conference, Barcelona, p. 1242 (1997).Google Scholar
Katagiri, H., Jimbo, K., Yamada, S., Kamimura, T., Maw, WS., Fukano, T., Ito, T. and Motohiro, T., Applied Physics Express 1, 041201 (2008).CrossRefGoogle Scholar
Todorov, T. K., Tang, J., Bag, S., Gunawan, O., Gokmen, T., Zhu, Y., and Mitzi, D. B., Adv. Energy Mater. 3, 34 (2013).CrossRefGoogle Scholar
Eberspacher, C., Fredric, C., Pauls, K., and Serra, J., Thin Solid Films 387, 18 (2001).CrossRefGoogle Scholar
Wada, T., Matsuo, Y., Nomura, S., Nakamura, Y., Miyamura, A., Chiba, Y., Yamada, A. and Konagai, M.. Phys. Stat. Sol. (a) 203, 2593 (2006).CrossRefGoogle Scholar
Kubo, J., Matsuo, Y., Wada, T., Yamada, A., and Konagai, M., Thin-Film Compound Semiconductor Photovoltaics-2009, (Mater. Res. Soc. Symp. Proc. Vol. 1165 ), 1165-M05-13.Google Scholar
Wada, T., Kinoshita, H., and Kawata, S., Thin Solid Films 431–432, 11 (2003).CrossRefGoogle Scholar
Wada, T. and Kinoshita, H., J. Phys. Chem. Solids 66, 1987 (2005).CrossRefGoogle Scholar
Wada, T., Kubo, J., Yamazoe, S., Yamada, A., and Konagai, M., Proc. 25th European Photovoltaic Solar Energy Conference and Exhibition/5th World Conference on Photovoltaic Energy Conversion (Valencia), p. 3465 (2010).Google Scholar
Gao, F., Yamazoe, S., Maeda, T., and Wada, T., Jpn. J. Appl. Phys. 51, 10NC28 (2012).CrossRefGoogle Scholar
Gao, F., Yamazoe, S., Maeda, T., Nakanishi, K., and Wada, T., Jpn. J. Appl. Phys. 51, 10NC29 (2012).CrossRefGoogle Scholar
Katagiri, H., Jimbo, K., Tahara, M., Araki, H. and Oishi, K., Thin-Film Compound Semiconductor Photovoltaics-2009, (Mater. Res. Soc. Symp. Proc. Vol. 1165 ), 1165-M04-01.Google Scholar