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Published online by Cambridge University Press: 01 February 2011
In this work, a possibility to further suppress silicon vapor condensation and formation of Si clusters in order to improve the growth rate and morphology during the low-temperature halo-carbon epitaxial growth of 4H-SiC was investigated. While a pronounced dissociating of Si clusters was clearly demonstrated, the enhancement of the growth rate and morphology was less significant then expected. In addition, the homogeneity of the growth rate and doping along the gas flow direction indicated that a significant and non-equal depletion of Si and C growth species takes place at sufficiently high HCl supply. HCl flow-dependent formation of polycrystalline Si and SiC deposits in the upstream portion of the hot zone was shown to be the source of this depletion.