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Growth and Characterization of ZnO Thin Film by RF Magnetron Sputtering for Photoacoustic Tomography Sensor

Published online by Cambridge University Press:  15 February 2013

Takuya Matsuo
Affiliation:
Graduate School of Engineering, Tohoku University, Sendai, Miyagi 980-8579, Japan
Shuhei Okuda
Affiliation:
Graduate School of Engineering, Tohoku University, Sendai, Miyagi 980-8579, Japan
Katsuyoshi Washio
Affiliation:
Graduate School of Engineering, Tohoku University, Sendai, Miyagi 980-8579, Japan
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Abstract

To apply thin ZnO film to photoacoustic tomography sensors, we investigated methods to improve its piezoelectricity with high optical transmittance. ZnO film was deposited by RF magnetron sputtering on a quartz substrate with various changes of the following conditions: RF sputtering power, Ar gas pressure, and substrate temperature (TSUB). The preliminary optimization of sputtering conditions is to form the ZnO film with good c-axis crystalline alignment. The results of X-ray diffraction measurement and cross-sectional observations indicated that the high-TSUB condition was preferable. This was because the desorption of Zn due to high-TSUB during the deposition process induced the formation of excellent columnar grains normal to the substrate. To enhance the piezoresponse, the substitution of Zn with different crystal-radius atoms was investigated, the aim being to increase the electrically neutral dipole moment by the partial displacement of the Zn-O bond. The transition metal V, with the potential to have the various configurations and coordination numbers, was selected as the dopant. As a result, it was confirmed that the diffraction peak from the (002) plane shifted to low angles with small degradation of the diffraction intensities.

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Articles
Copyright
Copyright © Materials Research Society 2013 

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References

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