Published online by Cambridge University Press: 21 February 2011
Competing desorption during the epitaxial growth of Cu on the W(110) surface has been studied with low energy electron microscopy (LEEM). Direct imaging of a structural transformation from pseudomorphic (1×1) to relaxed (15×1) periodicity which occurs at a coverage of θCu = 2.13 monolayers is used as a very accurate, local probe of coverage during deposition. The desorption energy E = 3.67 eV and attempt frequency v = 2.15 × 1015 s−1 are determined by examining the balance condition when the incident and desorption fluxes are equal. A step-flow-like growth morphology occurs when the supersaturation is significantly reduced by competing desorption. An island nucleation and coalescence growth morphology results at higher supersaturation.