Published online by Cambridge University Press: 21 February 2011
We have investigated different solution techniques to synthesize the Cu-based superconductors in the thick film form. Thick films of YBa2Cu3O7 have been produced using controlled precipitation techniques. Bi-based and Tl-based materials have been deposited by spraying of ionic solutions. The numerous difficulties encountered during each process are analyzed in order to propose new synthesis procedures such as a new method, based on the precipitation of hydroxides only, which is described as a prospective for lowering the synthesis temperature and shortening the reaction time.