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Imprinting the Quasi Bookshelf Texture of a Ferroelectric Liquid Crystal into Nano-scaled Polymer Fibrils

Published online by Cambridge University Press:  15 March 2011

S. H. Kim ,
S. Suresh  and
L.-C. Chien
S. H. Kim
Affiliation:
Chemical Physics Interdisciplinary Program and Liquid Crystal InstituteKent state University, Kent, Ohio 44242
S. Suresh
Affiliation:
Chemical Physics Interdisciplinary Program and Liquid Crystal InstituteKent state University, Kent, Ohio 44242
L.-C. Chien
Affiliation:
Chemical Physics Interdisciplinary Program and Liquid Crystal InstituteKent state University, Kent, Ohio 44242
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Abstract

Polymer-stabilized ferroelectric liquid crystals (PSFLCs) are made by photopolymerizing 3% reactive mesogenic monomer on a quasi bookshelf texture of a ferroelectric liquid crystal (FLC). We observe the formation of nano-scaled polymer fibrils templated by the two dimensionally ordered host. The polymer fibrils capture the orientation of the host with thin polymer fibrils interweaving the smectic layers. The SEM study highlights the difference in morphology of the polymer fibrils depending on polymerization conditions; that is, polymerizing with or without the presence of an electric field. The polymer networks suppress the cone of rotation of FLC and thus, facilitate the switching and shorten the response time of the PSFLCs. We observed the threshold-less switching behavior in PSFLCs from samples polymerized with and without the field.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 709: Symposium CC – Advances in Liquid Crystalline Materials and Technologies , 2001 , CC1.7.1
Copyright
Copyright © Materials Research Society 2002

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References

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